Effects of Ni content and heat treatment condition on impact toughness and creep strength of precipitation strengthened 15Cr ferritic steels were investigated in order to discuss a possibility of improvement in both mechanical properties. Both creep strength and impact toughness of the developing steels were improved drastically by solid solution treatment with water quenching. However, an addition of Ni reduced the long-term creep strength of the steels, though Ni was effective in improvement in impact toughness. It was found that water quenching suppressed formation of coarse block type particles and precipitate free zones around them, and precipitation of plate type fine particles and thermal stability of them within ferrite phase were promoted by solid solution treatment with water quenching. However, martensite phase with sparsely distributed coarse block type particles were formed in the Ni added steels, and such microstructure reduced the precipitation strengthening effect slightly. On the other hand, increase in impact values of the steel indicated no relation to volume fraction of martensite phase. It was supposed that the impact toughness of ferrite phase itself was improved by solid solution treatment and addition of Ni.

9-12%Cr martensitic steels can be applied to the next highest temperature components such as boiler tracts, steam pipelines and turbines of advanced ultra-supercritical power plants with steam temperatures of 650°C. New 10%Cr martensitic steels with high B and low N contents can be a worthy candidate for use in production because it has superior creep resistance. At the same time, resistance to cyclic and dynamic loads is very important. In this work, we studied the low cycle fatigue (LCF) properties at room and elevated (500-650°C) temperatures and Charpy impact toughness at temperatures ranging from -196…100°C of advanced 10% Cr martensitic steel with high B and low N contents. The effect of new alloying scheme and corresponding peculiarities of M 23 C 6 carbides on the low cycle fatigue resistance and impact toughness of the 10%Cr martensitic steel is analyzed. It is revealed that fine and densely distributed carbides has no effect on the fatigue resistance except for the slight improvement of fatigue life at small strain amplitudes and shift the ductile-brittle transition temperature (DBTT) to higher but satisfactory value of +10°C as compared to other high-chromium martensitic steels.

Nimonic 263 alloy was selected for gas turbine combustor transition piece due to its excellent high temperature mechanical performance. In present work, Nimonic 263 alloy plate with thickness of 5mm was welded using 263 filler metal by GTAW, then post weld heat treatment of 800℃/8h/air cool was carried out. The hardness and impact toughness of welded joints were measured, and the microstructure evolution after aging at 750℃ for 3000h was investigated by scanning electron microscopy(SEM). The results show that, during the aging process, the hardness of weld metal increases firstly and then decreases. The impact toughness decreases significantly at first and then increase. Furthermore, some fluctuations can be detected in hardness and impact toughness after long-term thermal exposure. The significant decrease in the impact toughness of the aged welded joints mainly results from the precipitation of η phase around grain boundary and intergranular MC phase. The hardness of weld metal increases due to the precipitation of more carbides and γ′ phase after 1000h aging, then decreases owing to the growth of γ′ phase after 3000h aging.

A compositional modification has been proposed to validate an alloy design which potentially eliminates the requirement of post-weld heat treatment (PWHT) while preserving the advantage of mechanical properties in a reduced activation bainitic ferritic steel based on Fe-3Cr-3W-0.2V- 0.1Ta-Mn-Si-C, in weight percent, developed at Oak Ridge National Laboratory in 2007. The alloy design includes reducing the hardness in the as-welded condition for improving toughness, while increasing the hardenability for preserving the high-temperature mechanical performance such as creep-rupture resistance in the original steel. To achieve such a design, a composition range with a reduced C content combining with an increased Mn content has been proposed and investigated. Newly proposed “modified” steel successfully achieved an improved impact toughness in the as- welded condition, while the creep-rupture performance across the weldments without PWHT demonstrated ~50% improvement of the creep strength compared to that of the original steel weldment after PWHT. The obtained results strongly support the validity of the proposed alloy design.

The microstructures of an advanced Ta-added 9Cr-3Co-2W-Mo steel with increased boron content that has been homogenized at different temperatures were investigated. The chains of coarse W-rich particles were observed in the steel after homogenization at 1150°C for 24 h. These particles remained in the microstructure after normalization and tempering. Such additional dispersion hardening in the initial state of the studied steel decreased the creep rate in transient region. However, the duration of steady state creep and overall creep time was increased in the samples homogenized at 1200°C. Despite of the presence of coarse W-rich particles, the impact toughness of the low-temperature- homogenized steel in the tempered condition was significantly higher than that of the steel homogenized at 1200°C

The long-term performance of superheater super 304h tube during the normal service of an ultra-supercritical 1000mw thermal power unit was tracked and analyzed, and the metallographic structure and performance of the original tube sample and tubes after 23,400h, 56,000h, 64,000 h, 70,000 h and 80,000 h service were tested. The results show that the tensile strength, yield strength and post-break elongation meet the requirements of ASME SA213 S30432 after long-term service, but the impact toughness decreases significantly. The metallographic organization is composed of the original complete austenite structure and gradually changes to the austenite + twin + second phase precipitates. With the extension of time, the number of second phases of coarseness in the crystal and the crystal boundary increases, and the degree of chain distribution increases. The precipitation phase on the grain boundary is dominated by M 23 C 6 , and there are several mx phases dominated by NbC and densely distributed copper phases in the crystal. The service environment produces a high magnetic equivalent and magnetic induction of the material, the reason is that there are strips of martensite on both sides of the grain boundary, and the number of martensite increases with the length of service.

In this study, 25Cr2Ni2Mo1V filler metal was deposited to weld low pressure steam turbine shafts, which are operated in fossil power plants. A comparison experiment was conducted on the weld metals (WMs) before and after varied various aging duration from 200 hours up to 5000 hours at 350 ℃. Microstructure was characterized by means of scanning electron microscopy (SEM) and electron back-scattered diffraction (EBSD) techniques. In addition, mechanical properties of corresponding specimens were evaluated, e.g. Vickers microhardness, Charpy V impact toughness and tensile strength. It is shown that the tensile strength remained stable while impact energy value decreased with increasing aging duration. Based on the experiment above, it was concluded that the variation of mechanical properties can be attributed to the redissolution of carbides and reduction of bainite lath substructure.

The efficiency of power plants is depending on the steam temperature and/or the steam pressure. Efficiency increasing from 35% to 42-45% require increasing of the steam temperature over 600°C and the pressure over 26 MPa. According to the designer opinion it is not profitable to use classical low alloy creep resistant steels 16Mo3, 13CrMo4-5 or 10CrMo9-10 for membrane waterwall construction for these service condition. New modified low alloy creep resistance T23 and T24 (7CrMoVTiB10-10) steels were developed for membrane waterwalls. Welding of these steels with small thickness (around 6.3 mm) should be enabled without preheating and post weld heat treatment (PWHT) due to the lower carbon content below 0.1%. High creep rupture strength (CRS) values are achieved by Ti, N and B elements alloyed to T24 steel. The original expectation that the welding small thickness without preheating was early overcome and was wrong. According to the present experience the T24 steel is welded with preheating at 150-250°C depending on the wall thickness and welded joint toughness in order to achieve required hardness and impact toughness values. Opinions on the T24 welded joints post weld heat treatment (PWHT) requirements are still inconsistent. Especially the membrane waterwalls of the supercritical power plants are still produced without PWHT.

This study investigates the mechanisms of temper embrittlement in 410 martensitic stainless steel, a material widely used in steam turbine blades due to its excellent corrosion resistance and high strength achieved through quenching and tempering heat treatments. While the material’s hardness and impact toughness strongly depend on tempering temperatures, significant embrittlement occurs around 540°C, manifesting as decreased Charpy impact energy alongside increased strength and hardness. To understand this phenomenon at the nanometer scale, high-resolution transmission electron microscopy (TEM) analysis was performed, focusing on electron diffraction patterns along the <110>α-Fe and <113>α-Fe zone axes. The analysis revealed distinctive double electron diffraction spots at 1/3(211) and 2/3(211) positions, with lattice spacing of approximately 3.5 Å—triple the typical α-bcc lattice spacing (1.17 Å). These regions were identified as metastable “zones” resembling ω-phase structures, potentially responsible for the embrittlement. While this newly identified phase structure may not fully explain the complex mechanisms of temper embrittlement, it provides valuable insights for developing improved alloying and heat treatment methods to mitigate embrittlement in martensitic steels.

In this paper, the performance of T23 and 12Cr1MoVG water wall tubes as well as their welded joints in engineering applications is reported. It was found that the T23 water wall tube may have water leak problems during its operation. In order to make sure the safe operation, leakage reasons of T23 water wall tube were analyzed and improvement measures were taken. Recommendations on the choice of water wall material of 1000MW USC tower boiler are given.

Super Duplex stainless steels (SDSS) are alloys based on the Fe-Cr-Ni-N system. The chemical composition is tailored to achieve a balanced microstructure of 50% ferrite and 50% austenite. Hyper Duplex Stainless Steels (HDSS) are also duplex materials distinguished by their remarkable yield strength (≥700 MPa) and corrosion resistance (PREN>48). They have been developed as an alternative to the well-established SDSS when superior mechanical and corrosion performance is required. This enhanced performance is attributed to alloying additions, primarily Cr, Mo, and N. In this study, a comparison is conducted between filler metals of SDSS and HDSS for the root welding of SDSS plates. The gas tungsten arc welding (GTAW) process was used to carry out root welding passes and Gas Metal Arc Welding (GMAW) for filling passes on SDSS substrates arranged in a V groove to simulate a repair scenario. The heat input was controlled in both processes, keeping it below 2.0 kJ/mm in the GTAW and 1.2 kJ/mm in the GMAW. GTAW with constant current was used and the parameters achieved producing full penetration welds with SDSS and HDSS. In this case, Nitrogen was used as backing gas to avoid oxidation of the root. Thus, a special GMAW-Pulsed version was applied to achieve good wettability and defect-free joints. ASTM G48 tests were performed to evaluate the corrosion resistance through Critical Pitting Testing (CPT) analysis on the root pass, microstructural analysis via optical microscopy, and impact toughness. Consequently, a comprehensive examination of the welded joints outlines manufacturing conditions, limitations, and the applications of SDSS and HDSS filler metals.

Inconel alloy 740H was specifically developed for use in coal-fired AUSC boilers. This alloy displays a unique combination of steam and coal-ash corrosion resistance, microstructure stability, creep strength and heavy section weldability. During the past two years Special Metals and Wyman-Gordon have undertaken an intense effort to demonstrate their capability to manufacture full-size boiler components, characterize their properties and simulate field assembly welds. This work was performed according to the requirements of ASME Boiler Code Case 2702 that was recently issued. This paper covers manufacturing of tube and pipe products and property characterization including recent data on the effect of long time exposure on impact toughness of base and weld metal. New data will also be reported on coal ash corrosion of base metal and weld metal. An overview of welding studies focused on integrity of circumferential pipe joints and a discussion of remaining technical issues will be presented.

Dissimilar metal welds between T91 ferritic steels and TP347H austenitic alloys are commonly used in fossil power plants in China. Premature failure of such dissimilar welds can occur, resulting in unplanned plant outages that can cause huge economic losses. In this article, microstructural evolution of T91/TP347H dissimilar welds after different service conditions were studied, mechanical properties before and after service were also analyzed, a full investigation into the failure cause was carried out. The results show, the dissimilar metal welds in the as-welded condition consists of a sharp chemical concentration gradient across the fusion line, failure is attributed to the steep microstructural and mechanical properties gradients, formation of interfacial carbides that promote creep cavity formation.

In dissimilar welds between martensitic stainless steel F6NM and nitrogen-strengthened austenitic stainless steel FXM-19, type 209 austenitic welding consumables are used to align with the mechanical properties and chemical composition of FXM-19, with F6NM welds requiring post-weld heat treatment (PWHT) to restore ductility and toughness, raising concerns about sigma embrittlement in ER209 butter welds. This study investigated the mechanical properties and microstructure of F6NM+FXM-19 dissimilar welds, finding no detrimental sigma phase formation in the butter (PWHT) and groove weld metal (as welded) across various welding processes, indicating no sigma phase transformation due to PWHT. Submerged arc welding (SAW) and gas tungsten arc welding (GTAW) demonstrated good mechanical properties, while Gas Metal Arc Welding with 100% Ar gas shield (GMAW 100% Ar) could not be properly evaluated due to weld defects. SAW and GTAW were deemed suitable for this dissimilar weld joint, with several welding processes providing acceptable results using ER209 filler material for fabricating pressure vessels requiring F6NM to XM-19 joints.

To operate future fusion power plants economically, the fusion community needs structural materials that can last longer and operate at higher temperatures than current materials, as well as better heat-dissipating components and a reliable supply chain for them. Additive manufacturing (AM) of existing reduced activation ferritic/martensitic steels (RAFMS) has the potential to solve these problems, which is why we developed a laser powder bed fusion (LPBF) process for Eurofer97 steel, demonstrating excellent mechanical properties (~30% improved yield strength, ~6300% improved creep rupture life, similar toughness and ductility compared to wrought Eurofer97) and low process scatter (relative standard error for yield, tensile strength and elongation on build plate <1%). The main remaining challenge is the consistent sourcing of quality Eurofer97 powder, but we have shown that this can already be done if the limits on impurity elements are slightly relaxed. Our work lays the groundwork for the manufacture of complex fusion components that can dissipate heat better and have a higher operating temperature thanks to the improved material properties. It also helps plug the current RAFMS supply chain gap, enabling easier component prototyping and small-scale manufacture that can smoothly scale in volume in the future.

Approximately 75% of the worldwide energy supply is based on fossil energy but the discussions on CO 2 emission require improvements of the conventional power technologies and also an increase of renewable energy resources. Over the past 40 years, enormous efforts, especially in the development of new materials, were made to establish the technology for the ultra-supercritical power plants, which are the standard of today’s power generation. For decades voestalpine Boehler Special Steel has been a full package supplier of customized high quality special steels and forgings with close relationships to plant manufacturers to provide products ahead of their time. This paper reports on improvements and research activities of the currently best available martensitic 9% Cr steel FB2 and the latest generation, the so-called MarBN steels, raising the operating temperatures of the 9% Cr steel class from 620 °C to 650 °C. Increasing the operating temperature requires adaptations in processes and manufacturing methods to adjust optimized microstructures with improved toughness properties and increased creep rupture strength at the same time. The microstructure of two Boron containing 9% Cr steels, FB2-2 and NPM1, developed within the framework of COST / KMM-VIN, have been investigated comparatively after different heat treatments and discussed after creep rupture tests at 650°C. The results show a dependency of the creep rupture strength on the stability of precipitates and the creep rupture time of both steels was increased by more than 30 % without negatively affecting the creep rupture strain and impact values.

This study investigates the impact of adding small amounts of rare earth (RE) elements on the properties and microstructures of SA335P91 steel welds. The RE elements were incorporated into the weld metal using a coating process. The researchers then proposed an optimal RE formula aimed at achieving improved properties and microstructures. To evaluate the effectiveness of this approach, various tests were conducted on both welds with and without RE additions. These tests included tensile testing (both at room and high temperatures), impact testing, metallographic analysis to examine the microstructure, determination of phase transformation points, scanning electron microscopy, and X-ray diffraction. The results revealed that the addition of RE elements has the potential to enhance the properties and modify the microstructure of SA335P91 welds.

Advanced Ultra-supercritical (A-USC) steam power-plant technology is being developed for better efficiency and lower emissions at 700°C and above, but is based mainly on Ni-based alloys. The ability to include lower-cost alloys with appropriate high-temperature performance should have substantial technological and economic benefits. CF8C-Plus is a cast austenitic stainless steel recently developed for other applications at 600-900°C, which has creep-strength comparable to many solid-solution Ni-based alloys. EPRI and Carpenter Technology produced a 400 lb heat of CF8C-Plus steel and hot-forged it at 5:1 and 12:1 reductions, to assess feasibility of the alloy as a wrought advanced stainless steel for potential use as steam headers and piping for A-USC power plant applications. The hot-forged alloy has a recrystallized grain structure 6-9 times finer than the as-cast dendritic structure, resulting in better strength and impact resistance at room-temperature, and about 20% higher yield-strength (YS) at 760°C, and similar or better ductility compared to the as-cast material. The initial creep-rupture testing at 700-800°C for up to 2000h also indicates similar or better rupture resistance and better creep-ductility for wrought compared to cast material. The next steps needed to test performance of the wrought austenitic stainless steel for extruded headers and piping are discussed.

Flux cored wires are worldwide used in power generation industry due to their technical and economic advantages. For welding P91 and P92 flux cored wires with a rutile slag system are available for several years. Results of long-term investigations up to 30.000 h show that specimens of all weld metal meet the requirements of the base material. Following the recent demand of reduced Mn+Ni content the chemical composition of all weld metal has been modified. For P91 a matching flux cored wire with Mn+Ni<1wt% and for P92 with Mn+Ni<1.2wt% is now available. In this paper the mechanical properties of all weld metal and welded joints are being presented. Latest developments in cast materials have shown that the so-called CB2 (GX13CrMoCoVNbNB 10-1-1) enables steam temperatures up to 620°C (1148°F). Therefore a matching flux cored wire with low Ni-content has been developed. Results of welding procedure qualification and first experience of manufacturing industrial components show the successful implementation of this new material grade and welding consumable.

As part of a Department of Energy (DOE) funded program assessing advanced manufacturing techniques for Small Modular Reactor (SMR) applications, the Nuclear Advanced Manufacturing Research Centre (AMRC) and the Electric Power Research Institute (EPRI) have been developing Electron Beam Welding (EBW) parameters and procedures based upon SA508 Grade 3 Class 1 base material. The transition shell, a complex component connecting the lower assembly to the upper assembly is a shell that flares up with varying thicknesses across its section. The component due to its geometry could be built by near net shape powder metallurgy hot isostatic pressing instead of conventional forging techniques. The demonstrator transition shell here is built from several sub-forging as a training exercise. The complex geometry and joint configuration were selected to assess the EBW as a suitable technique. This paper presents results from the steady state welding in the 60-110 mm material thickness range, showing that weld properties meet specification requirements. Weld quality was assured by Time-of-Flight Diffraction (ToFD). The transition shell was completed by welding a flange to the assembly. The presented transition shell assembly represents 6 welded sections all fabricated in below 100 min total welding time.