The construction of highly efficient, coal-burning Ultra Supercritical (USC) boiler systems to operate with steam temperatures up to 760°C (1400°F) and with steam pressures up to 35 MPa (5000 psi) will require the use of advanced high temperature, high strength materials. As part of a 5-year project to develop boiler materials for advanced USC power plants, principally funded by the Department of Energy (U.S. DOE No. DE-FG26-01NT41175) and the Ohio Coal Development Office (OCDO No. D-00-20), six alloys have been selected for development and implementation in USC boiler systems. The selected alloys are Haynes 230 (produced by Haynes International), Inconel 740 (produced by Special Metals Corp.), CCA 617 (produced by Krupp VDM GMBH), HR6W, Super 304H, and SAVE 12 (all three produced by Sumitomo Metal Industries). In this project, one of the goals has been to establish boiler fabrication guidelines for the use of these alloys. The principal objectives have been 1) to understand the behavior of these materials when subjected to conventional boiler fabrication processes, 2) to determine the thermomechanical treatments or other actions necessary to restore material properties which might degrade due to fabrication operations, and 3) to investigate prototypical manufacturing operations for producing both thick wall components (such as headers) and thin wall components (such as superheaters) from the USC alloys. This paper discusses some of the characteristics of these alloys, describes the technical approach used to assess their fabricability, and presents some of the results that have thus far been generated in this task effort.

Future, flexible thermal energy conversion systems require new, demand-optimized high-performance materials. In order to provide a basis for the targeted development of fatigue-resistant, cost-effective steel grades, the microstructural damage to materials and the failure of conventional and novel steels were investigated in thermo-mechanical fatigue and fatigue crack propagation experiments. Based on the results, improved, ferritic “HiperFer” (High performance Ferrite) steels were designed, produced and characterized. A brief description of the current state of development is given.

Increasing demand for reliable design of all kinds of structures requires materials properties evaluated under the conditions as close to real service conditions as possible. Presently resolved project dealing with development of new turbine blades geometry requires better understanding of the material behavior under service conditions. Service conditions of turbine blades are cyclic loading at high temperatures under superheated steam conditions and complex mechanical loading. There are not commercially available testing systems providing such functionality and thus the system allowing samples testing under considered conditions was developed. The system allows cyclic loading at temperatures up to 650°C under superheated steam conditions. Typical blade steel is investigated here and experimental approach considering complex mechanical loading as well as thermal and corrosion is shown here. The results of high cycle fatigue tests in superheated steam corrosive environment are shown here.

Solid particle erosion (SPE) harms steam and gas turbines, reducing efficiency and raising costs. The push for ultra-supercritical turbines reignited interest in SPE’s impact on high-temperature alloys. While the gas turbine industry researches methods to improve erosion resistance, a similar need exists for steam turbines. Existing room-temperature SPE test standards are insufficient for evaluating turbine materials. To address this gap, an EPRI program is developing an elevated-temperature SPE standard. This collaborative effort, involving researchers from multiple countries, has yielded a draft standard submitted to ASTM for approval. This presentation will detail the program, test conditions, and the draft standard’s development.

This study investigates the growth kinetics and spallation behavior of oxide scales formed under steam environments on alloys used in high-temperature plants. The influence of alloy composition is analyzed using two approaches: an empirical model based on the concept of “chromium equivalent” and a neural network model. Both models demonstrate a good correlation with experimental results when sufficient data is available to generate the model parameters. However, there is insufficient data on scale spallation to develop similar models describing the influence of alloy composition on this phenomenon.

Natural gas has long been regarded as the primary energy source for advanced power systems because of its cleanliness and highly efficient nature. Nevertheless, coal is gaining attention again as a stable energy source for power generation. In this paper, high efficiency pulverized coal power plant technology, especially materials and the design for high temperature turbine systems, is discussed. The development of materials has contributed to the high efficiency plant development, so far. The development of 12% Cr steel was key in building the state-of-the-art 600-deg C class steam turbine system. It is believed that a 700-deg C class steam turbine system will be realized with Ni-based super alloys and austenitic steels. In the near future, the system with a 700-deg C reheat temperature and 630-deg C main steam temperature is promising for the pulverized coal power plant because of the need for only moderate development work, low capital expenditure, and its high efficiency.

A 10%Cr martensitic steel for rotor applications, COST FB2, was used in 620°C steam turbines for about four years in China. In order to increase the unit efficiency to 50% of the coal-fired power plant, an advanced 630°C steam turbine developed by DongFang Turbine Co., Ltd will be put into operation in 2021. A three-ton middle-scale prototype turbine rotor forging (3387FC1) was developed and evaluated through the collaborative work of DongFang Turbine and the Japan Steel Works (JSW) using JMATR, a high-performance heat-resistant steel developed by JSW. Test results for the prototype rotor, including homogeneity of chemical composition, ultrasonic tests, mechanical properties, and long-term creep behaviors, and microstructure, are presented and discussed.

The oxidation behavior of X20 steel in steam environments was studied isothermally between 580-640°C. Initially, the magnetite (Fe 3 O 4 ) phase formed on the surface. With increasing time and temperature, the hematite (Fe 2 O 3 ) phase formed. The oxide scale consisted of an inner layer divided from an outer layer by the original metal surface. A Cr-rich area was observed beneath the original metal surface. Oxide scales formed on a serviced boiler tube at 540°C for 7000h were also analyzed and found to be similar in oxide phase composition to those formed on X20 steel under laboratory conditions. However, differences existed in the microstructure and distribution of the Cr-rich area within the oxide scale. It was concluded that the oxidation mechanism under field conditions differs from that under laboratory conditions.

Supercritical carbon dioxide cooling during machining has been identified as an effective measure to mitigate the risk of stress corrosion cracking in materials utilized in the primary circuit of light water reactors, particularly in pressure vessel structural steels. This study aims to compare two different cooling methods, the novel supercritical carbon dioxide and conventional high pressure soluble oil, employed during both milling and turning processes for SA508 Grade 3 Class 2 and AISI 316L steels. As the surface conditions of materials are critical to fatigue properties, such as crack initiation and endurance life, the fatigue performance of both cooling methods for each process were then evaluated and the impact on properties determined. To compare the potential benefits of supercritical carbon dioxide cooling against conventional soluble oil cooled machining, fatigue specimens were machined using industry relevant CNC machine tools. Surface finish and machining methods were standardized to produce two different specimen types, possessing dog- bone (milled) and cylindrical (turned) geometries. Force-controlled constant amplitude axial fatigue testing at various stress amplitudes was undertaken on both specimen types in an air environment and at room temperature using a stress ratio of 0.1. The fatigue performance of the supercritical carbon dioxide cooled specimens revealed substantially greater endurance lives for both SA508 and 316L materials, when compared with specimens machined using high pressure soluble oil cooling.

The creep rupture properties of welded joints of advanced 9%Cr-Mo-Co-B steel used for 620°C USC steam turbine have been studied. The welded joints were prepared by means of shielded metal arc welding (SMAW). A lot of creep tests have been conducted and the results indicate that fracture usually occurs in the intercritical heat affected zone (ICHAZ) of the welded joint and is typical of Type IV cracking. The microstructure of the HAZ has been investigated by using optical microscopy, SEM and TEM. The degradation mechanism of welded joint of the 9%Cr-Mo-Co-B steel has been explored by analysing the phases of precipitates. Creep voids were observed in the vicinity of the coarse Laves phase particles, resulting in the degradation of the creep rupture properties.

India's current installed power generating capacity is about 225,000 MW, of which about 59% is coal based. It is projected that India would require an installed capacity of over 800,000 MW by 2032. Coal is likely to remain the predominant source of energy in India till the middle of the century. India is also committed to reducing the CO 2 emission intensity of its economy and has drawn up a National Action Plan for Climate Change, which, inter alia, lays emphasis on the deployment of clean coal technologies. With this backdrop, a National Mission for the Development of Advanced Ultra Supercritical Technology has been initiated. The Mission objectives include development of advanced high temperature materials, manufacturing technologies and design of equipment. A corrosion test loop in an existing plant is also proposed. Based on the technology developed, an 800 MW Demonstration A-USC plant will be established. Steam parameters of 310 kg/cm 2 , 710 °C / 720 °C have been selected. Work on selection of materials, manufacture of tubes, welding trials and design of components has been initiated. The paper gives details of India's A-USC program and the progress achieved.

Austenitic and super-austenitic stainless steels are a critical component of the spectrum of high temperature materials. With respect to power generation, alloys such as Super 304H and NF709 span a gap of capability between ferritic and martensitic high chromium steels and nickel-based alloys in boiler tube applications for both conventionally fired boilers and heat-recovery steam generators (HRSG). This research explores a wrought version of a cast austenitic stainless steel, CF8C-Plus or HG10MNN, which offers promise in creep strength at relatively low cost. Various manufacturing techniques have been employed to explore the impact of wrought processing on nano-scale microstructure and ultimately performance, especially in high temperature creep. Transmission electron microscopy has been used to quantify and characterize the creep-strengthening particles examining the relationship between traditional melting and extrusion as compared to powder metallurgy.

In the test loop HWT II (High Temperature Materials Test Loop) installed in the fossil power plant Grosskraftwerk (GKM) Mannheim in Germany, thick-walled components made of nickel base alloys were operated up to temperature of 725 °C. The operation mode chosen (creep-fatigue) was to simulate a large number of start-ups and shutdowns with high gradients as expected for future high efficient and flexible power plants and to investigate the damage due to thermal fatigue of the used nickel base alloys. In this paper the damage evolution of a header made of the nickel base alloys Alloy 617 B and Alloy C263, which was a part of HWT II test rig, were investigated using nondestructive and destructive techniques. Furthermore, the damage has been considered and evaluated by using numerical methods. In addition, different lifetime assessment methods of standards and recommendations with focus on creep-fatigue damage were used and evaluated. The different lifetime models are applied to the header and the results were compared to the results of metallographic investigations and damage observations.

The “Cool Earth-Innovative Energy Technology Program,” launched by the Japanese government in March 2008, aims to significantly reduce global greenhouse gas emissions. Among the 21 selected technologies is the Advanced Ultra Super Critical (A-USC) pressure power generation, which targets the commercialization of a 700°C class pulverized coal power system with a power generation efficiency of 46% by around 2015. As of 2004, Japan's pulverized coal power plant capacity reached 35 GW, with the latest plants achieving a steam temperature of 600°C and a net thermal efficiency of approximately 42% (HHV). Older plants from the 1970s and early 1980s, with steam temperatures of 538°C or 566°C, are nearing the need for refurbishment or rebuilding. A case study on retrofitting these older plants with A-USC technology, which uses a 700°C class steam temperature, demonstrated that this technology is suitable for such upgrades and can reduce CO 2 emissions by about 15%. Following this study, a large-scale development of A-USC technology began in August 2008, focusing on developing 700°C class boiler, turbine, and valve technologies, including high-temperature material technology. Candidate materials for boilers and turbine rotor and casing materials are being developed and tested. Two years into the project, useful test results regarding these candidate materials have been obtained, contributing to the advancement of A-USC technology.

Nitridation is a high-temperature material degradation issue that can occur in air and in environments containing nitrogen, ammonia, etc., and in a variety of industrial processes. The nitridation behavior of several commercial nickel- and cobalt-based alloys is reviewed in this paper. The alloys include Haynes 230, Haynes 188, Haynes 625, Haynes 617, Haynes 214, Hastelloy X, and Haynes 233. The environments discussed are high-purity nitrogen gas between 871°C and 1250°C, 100% ammonia gas at 982°C and 1092°C, and a simulated combustion atmosphere at 982°C. The results showed that nitridation occurred in all the environments containing nitrogen. The nitridation attack was strongly influenced by the alloy compositions and the type of oxide formed (i.e., chromia or alumina), as some degree of oxidation was expected in the environments in which residual oxygen was present. Thermal cycling is briefly discussed because the integrity of protective oxides is also an important factor in resisting high-temperature oxidation and nitridation attack.

Listings of the conference executive committee, international advisory board, and technical review committee for the 2019 Joint EPRI – 123HiMAT International Conference on Advances in High-Temperature Materials.

The powder metallurgy (P/M) process has been applied to a high strength turbine disk alloy. It is known that P/M alloys show characteristic microstructures such as prior powder boundaries (PPB) compared to microstructures of conventional cast and wrought (CW) alloys. High temperature tensile tests were conducted on CW and P/M processed alloy720Li in order to reveal the effect of temperature and strain rate on deformation behavior and to demonstrate the effect of microstructure derived from P/M process on deformability. The fracture mode of the P/M material changed from grain interior fracture to fracture around large PPB with an increment of strain rate. In addition, samples ruptured at higher temperature showed grain boundary fracture regardless of strain rate. On the other hand, the CW material showed good deformability with chisel point fracture in the entire temperature and strain rate condition range. In the P/M material, melting of grain boundaries occurred at super solvus temperature conditions. Large PPB acts as nucleation site of voids at higher strain rate conditions. Precipitation strengthening by γ’ phase degrades deformability at sub solvus temperature conditions. However, deformability near the solvus temperature and low strain rate condition in as HIPed P/M material increased with fine grain size distribution in spite of the presence of large grains resulting from PPB.

To meet worldwide emission targets many Government policies either avoid the use of coal burning plant for future energy production, or restrict emissions per kilogram of coal consumed beyond the capability of most conventional plant. As a result this has accelerated current worldwide developments of steel and nickel alloys for coal-fired plant to operate at temperatures in excess of 625°C. Within the UK a modified 9%Cr steel has been developed which is based on the MarBN steel first proposed by Professor Fujio Abe of NIMS Japan, and has been designated IBN-1. The steel is modified by additions of, typically, 3% cobalt and tungsten with controlled additions of boron and nitrogen. While development of 9%Cr steels has continued since the last EPRI high temperature material conference in 2016 (Portugal), parallel developments in nickel alloy castings for even higher temperature and pressure applications have also continued. This paper summarises the latest developments in both of these material types.

Ni-38Cr-3.8Al has high hardness and high corrosion resistance with good hot workability, and therefore, it has been applied on various applications. However, in order to expand further application, it is important to understand the high temperature properties. Then, this study focused on the high temperature properties such as thermal phase stability, hardness, tensile property, creep property and hot corrosion resistance. As the result of studies, we found that the thermal phase stability of (γ/α-Cr) lamellar structure and the high temperature properties were strongly influenced by the temperature. Although the high temperature properties, except for creep property, of Ni-38Cr-3.8Al were superior to those of conventional Ni-based superalloys, the properties were dramatically degraded beyond 973 K. This is because the lamellar structure begins to collapse around 973 K due to the thermal stability of the lamellar structure. The hot corrosion resistance of Ni-38Cr-3.8Al was superior to that of conventional Ni-based superalloys, however, the advantage disappeared around 1073 K. These results indicate that Ni-38Cr-3.8Al is capable as a heat resistant material which is required the hot corrosion resistance rather than a heat resistant material with high strength at high temperature.

Materials are the key to develop advanced ultra-supercritical (A-USC) steam generators. Operating at temperature up to 760°C and sustained pressure up to 4500 psi. Pressure vessel and piping materials may fail due to creep, oxidation, and erosion. Valves are particularly subjected to loss of function and leakage due to impermeant of the sealing surfaces. New materials, less susceptible to the above damage modes are needed for A-USC technology. Two Ni-based superalloys have been identified as prime candidates for valves based materials. Hardfacing is applied to sealing surfaces to protect them from wear and to reduce friction. Stellite 6 (Cobalt-based alloy) is the benchmark hardfacing owing to its anti-galling properties. However, the latest results tend to indicate that it is not suitable for high pressure application above 700°C. An alternative hardfacing will be required for A-USC. New Ni- and Co- based alloys are being developed for applications where extreme wear is combined with high temperatures and corrosive media. Their chemistry accounts for the excellent dry-running properties of these alloys and makes them very suitable for use in adhesive (metal-to- metal) wear. These new alloys have better wear, erosion, and corrosion resistance than Stellite 6 in the temperature range 800°C ~ 1000°C. As such, they have the potential to operate in A-USC. Velan recently developed an instrumented high temperature tribometer in collaboration with Polytechnique Montreal to characterize new alloys including static and dynamic coefficients of friction up to 800°C. We present herein the methodology that has been devolved to explore the effects of elevated temperature on the tribological behavior of those advanced material systems, with the goal of capturing the basis for the specification, design, fabrication, operation, and maintenance of valves for A-USC steam power plants.