Carbon migration in narrow-gap welding joints of dissimilar steels has been studied using bead-on-plate specimens to determine the factors that influence the formation of a soft ferrite structure in the carbon-depleted zone. Carbon migration was found to occur during tempering, with a ferrite structure formed at the intersection of multiple layers due to severe carbon migration. This was attributed to a steep gradient in Cr content caused by the low fusion penetration at the intersection. Experimental results and the relationship between fusion penetration and weld bead alignment confirmed that low fusion penetration is the main cause of ferrite-structured carbon depleted zones.

In a European ultra-supercritical (USC) power station repaired reheater bundle tubes made out of 25% Chromium stainless steels developed stress relief damages at the tube-to-tube butt welds, leading to leakages after only 8.500 hours of operation. Laboratory investigations of the leakages revealed common features of stress relief cracking (SRC) such as highly localized intergranular cracking in the heat affected zone (HAZ) near the fusion line, creep void formation at the crack tip and around the crack. At that time no other SRC damages were known for the employed 25% Chromium stainless steel boiler tubes. This article briefly describes the SRC damage found on the repaired reheater bundle tubes. It further provides insight on the several laboratory tests employed to assess the SRC behavior of welded joints of different creep resistant stainless steels. Among the selected test methods were Slow-Strain-Rate-Tests (SSRT), static 3-point bending tests derived from the Van Wortel approach and component tests. The results provided by the described tests methods have shown that the SRC behavior of a given material combination must be assessed by different techniques. This is especially the case for the evaluation of potential countermeasures and for the determination of the service conditions leading to the highest susceptibility.

This paper investigates creep rupture and damage behaviors of HR6W weldment using full thickness specimen cut from the circumferentially welded pipe. Creep tests were conducted at 750°C for durations up to 8,000 hours, and damage morphology of weldment during creep was characterized. The applicability of several nondestructive detection methods to the creep damage evaluation was discussed. It was found that full thickness specimen was broken at the base metal and main crack was inclined approximately at 45 degrees to the axial direction of the specimen. Times to creep rupture of full thickness specimen were comparable with those of the standard specimen. In addition, a small crack in base metal on the outer surface was first observed at life fraction of 35% by replication. PT can detect the crack in about half of the life. The crack whose length is longer than 3mm can be detected by UT in latter half of the life.

CrMoV cast steels are widely utilized for steam turbine and valve casings, and are subjected to operating and loading conditions which can promote damage mechanisms such as thermal fatigue, creep, erosion, etc. These components are subjected to variable, and sometimes severe conditions because of flexible operation. Therefore, there is a growing need for weld repair techniques including those which do not mandate post weld heat treatment (PWHT), e.g. so-called ‘temper bead’ weld repair. In this study, a simulated weld repair was performed using a temper bead technique. The maximum hardness in the heat affected zone (HAZ) CrMoV steel was ≤400HV. The integrity of the repair methodology was investigated using destructive testing, including hardness mapping, Charpy impact tests, tensile tests, low cycle fatigue and cross-weld creep, and the microstructure was assessed using light optical microscopy and scanning electron microscopy (SEM).

In recent years continuous and extensive research and development activities have been being done worldwide on 700°C A-USC (Advanced Ultra Super Critical) power plants to achieve higher efficiency and reduce the CO 2 emission. Increasing steam temperature and pressure of such A-USC boilers under consideration require the adoption of Ni based alloys. In the Japanese national project launched in 2008, Ni based alloy HR6W (45Ni-23Cr-7W-Ti, ASME Code Case 2684) is one of the candidate materials for boiler tube and pipe as well as Alloy617, Alloy263 and Alloy740H. The most important issues in A-USC boiler fabrication are the establishment of proper welding process for thick wall components of these alloys and verification of the long term reliability of their weldments. In our previous study, the weldability of HR6W was investigated and the welding process for Ni based thick wall pipe was established with the narrow gap HST (Hot wire Switching TIG) welding procedure originally developed by Babcock-Hitachi K.K. In this paper, creep rupture strengths of HR6W weldment were verified by the long term test up to 60,000 hours for tube and 40,000 hours for pipe. In Japanese national project, narrow gap HST welding process was also applied to the welding test for the other Ni based candidate pipe materials. Furthermore, as the practical A-USC boiler manufacturing trials, header mockup test was conducted and qualified for HR6W.

The necessity to reduce carbon dioxide emissions of new fossil plant, while increasing net efficiency has lead to the development of not only new steels for potential plant operation of 650°C, but also cast nickel alloys for potential plant operation of up to 700°C and maybe 750°C. This paper discusses the production of prototype MarBN steel castings for potential plant operation up to 650°C, and gamma prime strengthened nickel alloys for advanced super critical plant (A-USC) operation up to 750°C. MarBN steel is a modified 9% Cr steel with chemical concentration of Cobalt and tungsten higher than that of CB2 (GX-13CrMoCoVNbNB9) typically, 2% to 3 Co, 3%W, with controlled B and N additions. The paper will discuss the work undertaken on prototype MarBN steel castings produced in UK funded research projects, and summarise the results achieved. Additionally, within European projects a castable nickel based super alloy has successfully been developed. This innovative alloy is suitable for 700°C+ operation and offers a solution to many of the issues associated with casting precipitation hardened nickel alloys.

The use of high-nickel superalloys has greatly increased among many industries. This is especially the case for advanced coal-fired boilers, where the latest high temperature designs will require materials capable of withstanding much higher operating temperatures and pressures than current designs. Inconel alloy 740H (UNS N07740) is a new nickel- based alloy that serves as a candidate for steam header pipe and super-heater tubing in coal-fired boilers. Alloy 740H has been shown to be capable of withstanding the extreme operating conditions of an advanced ultra-super-critical (AUSC) boiler, which is the latest boiler design, currently under development. As with all high nickel alloys, welding of alloy 740H can be very challenging, even to an experienced welder. Weldability challenges are compounded when considering that the alloy may be used in steam headers, where critical, thick-section and stub-to-header weld joints are present. This paper is intended to describe the proper procedures developed over years of study that will allow for ASME code quality welds in alloy 740H with matching composition filler metals.

The use of the bainitic creep strength enhanced ferritic steel T/P23 has increased over the last decade in a wide range of applications including headers, superheater and reheater tubing and in waterwall tubing. Many issues have been reported in weldments of this material, such as hydrogen induced cracking, reheat cracking and stress corrosion cracking. In order to help characterize high temperature cracking phenomena, including reheat cracking, a limited number of laboratory creep crack growth tests are being conducted as part of an ongoing project. Tests were run on as-welded sections with the test specimen crack-tip located in select zones of the weldment. Test temperatures are intended to bookend the range of applications from a waterwall condition of ~482°C (900°F) to the superheat/reheat condition of 565°C (1050°F). This paper describes the results of some early testing at 482°C (900°F). The tests provided useful insight into the cracking susceptibility of the material at this temperature with respect to not only time-dependent cracking, but also fatigue crack growth and fracture toughness. The paper includes details of the test method and results, as well as findings from post-test metallographic examinations of the tested specimens.

Qualifying welding procedures for repair of components in high temperature service requires careful consideration of factors including identification of the materials involved, existing mechanical properties and service operating parameters such as temperature, pressure and environment. Selection of weld metals to match, under match or overmatch base material as well as direct and indirect consequences on the heat-affected zone also require evaluation. Application of post weld heat treatment and ramifications where dissimilar base materials are involved are discussed plus the necessity of conducting tests at the operating temperatures and conditions where information is not available from the literature. Each of these factors is discussed and examples provided.

In order to improve thermal efficiency of fossil-fired power plants through increasing steam temperature and pressure high strength martensitic 9-12%Cr steels have extensively been used, and some power plants have experienced creep failure in high temperature welds after several years operations. The creep failure and degradation in welds of longitudinally seam-welded Cr- Mo steel pipes and Cr-Mo steel tubes of dissimilar metal welded joint after long-term service are also well known. The creep degradation in welds initiates as creep cavity formation under the multi-axial stress conditions. For the safety use of high temperature welds in power plant components, the complete understanding of the creep degradation and establishment of creep life assessment for the welds is essential. In this paper creep degradation and initiation mechanism in welds of Cr-Mo steels and high strength martensitic 9-12%Cr steels are reviewed and compared. And also since the non-destructive creep life assessment techniques for the Type IV creep degradation and failure in high strength martensitic 9-12%Cr steel welds are not yet practically established and applied, a candidate way based on the hardness creep life model developed by the authors would be demonstrated as well as the investigation results on the creep cavity formation behavior in the welds. Additionally from the aspect of safety issues on welds design an experimental approach to consider the weld joint influence factors (WJIF) would also be presented based on the creep rupture data of the large size cross-weld specimens and component welds.

The susceptibilities of hot cracking and reheat cracking of A-USC candidate Ni-based alloys were evaluated relatively by Trans-Varestraint testing and Slow Strain Rate Tensile (SSRT) testing. In addition, semi-quantitative evaluation of the stress relaxation cracking susceptibility of Alloy 617 was conducted, because stress relaxation cracking in the heat affected zone (HAZ) has actually been reported for repair welds in Alloy 617 steam piping in European A-USC field-testing. Solidification cracking susceptibilities of Alloy 617 were the highest; followed by HR35, Alloy 740 and Alloy 141, which were all high; and then by HR6W and Alloy 263, which were relatively low. In addition, liquation cracking was observed in the HAZ of Alloy 617. The reheat cracking susceptibilities of Alloy 617, Alloy 263, Alloy 740 and Alloy 141 were somewhat higher than those of HR6W and HR35 which have good creep ductility due to the absence of γ’ phase precipitates. A method to evaluate stress relaxation cracking susceptibility was developed by applying a three-point bending test using a specimen with a V-notch and finite element analysis (FEA), and it was shown that stress relaxation cracking of aged Alloy 617 can be experimentally replicated. It was proposed that a larger magnitude of creep strain occurs via stress relaxation during the three-point bending test due to a higher yield strength caused by γ’ phase strengthening, and that low ductility due to grain boundary carbides promoted stress relaxation cracking. The critical creep strain curve of cracking can be created by means of the relationship between the initial strain and the creep strain during the three-point bending tests, which were calculated by FEA. Therefore, the critical conditions to cause cracking could be estimated from the stress relaxation cracking boundary from of the relationship between the initial strain and the creep strain during the three-point bending test.

Xcel Energy’s Comanche Unit 3 experienced widespread cracking of T23 membrane wall tubes within the evaporator section, initially occurring during the boiler construction phase, primarily at shop and field tube butt welds. The majority of the tube cracking was attributed to stress-corrosion cracking (SCC), and a lesser number of fabrication-related hydrogen induced cracking (HIC), weld solidification cracking, and brittle cracking within tube swage sections were also experienced. Hundreds of tubes were replaced prior to Unit commissioning, due to both actual tube leaks and those replaced due to weldment cracking and other identified weld defects during radiographic testing. Elevated stress levels and material susceptibility (i.e. hardness in the as-welded condition) were considered the critical factors in the tube cracking.

As flux cored wires for gas metal arc welding offer several technical and economic advantages they are becoming more and more popular. Matching flux cored wires for welding P92 have already been available for several years. A matching flux cored wire for welding the Co-alloyed cast steel CB2, which is used for turbine and valve casings operating at steam temperatures of up to 620°C, was developed recently. To connect casings with P92 pipes, dissimilar welding of CB2 to P92 is necessary. This can be done with filler metal that matches either CB2 or P92. Pre-tests have confirmed that flux cored arc welding (FCAW) can generally be used for dissimilar joint welding of CB2 to P92. To evaluate creep rupture strength dissimilar welds were performed with filler metal matching CB2 and P92, respectively. TIG welding was used for the root and the second pass and FCAW for the intermediate and final passes. Cross-weld tensile tests, side bend tests and impact tests of weld metals and heat-affected zones were carried out at ambient temperatures after two post-weld heat treatments (PWHT), each at 730°C for 12 hours. Creep rupture tests of cross-weld samples were performed at 625°C. This study compares the results of the mechanical tests at ambient temperature and the creep rupture tests, and discusses why P92 filler metals are preferred for such welds.

Nimonic 263 alloy was selected for gas turbine combustor transition piece due to its excellent high temperature mechanical performance. In present work, Nimonic 263 alloy plate with thickness of 5mm was welded using 263 filler metal by GTAW, then post weld heat treatment of 800℃/8h/air cool was carried out. The hardness and impact toughness of welded joints were measured, and the microstructure evolution after aging at 750℃ for 3000h was investigated by scanning electron microscopy(SEM). The results show that, during the aging process, the hardness of weld metal increases firstly and then decreases. The impact toughness decreases significantly at first and then increase. Furthermore, some fluctuations can be detected in hardness and impact toughness after long-term thermal exposure. The significant decrease in the impact toughness of the aged welded joints mainly results from the precipitation of η phase around grain boundary and intergranular MC phase. The hardness of weld metal increases due to the precipitation of more carbides and γ′ phase after 1000h aging, then decreases owing to the growth of γ′ phase after 3000h aging.

Steam turbine is one of the critical equipments in coal-fired power plants, steel P91 is a common material of its control valves. CoCr-based hardfacing on valve seats can resist long time exposure to water vapor with high temperature, thermal fatigue and solid particles erosion under high pressure. However, these hardfacing can crack and disbond during operation, which generates high risks for turbine systems and power plants. This article discussed the failure reasons of CoCr-based hardfacing, and introduced a method and practical experience of on-site repairing steam turbine valve seats with laser cladding NiCr coating.

The global electric power production is largely dependent on the operation of fossil-fired generation units. Many coal-fired units are exceeding 300,000 hours, which is beyond the expected design life. This has caused a continuous need to inspect steam touched components operating at high temperature and pressure. State-of-the-art coal and combined cycle gas units are specifying ever-greater amounts of the Creep Strength Enhanced Ferritic (CSEF) steels such as Grade 91 or Grade 92. The martensitic 9%Cr CSEF steels were developed to provide greater strength than traditional low alloy power plant steels, such as Grades 11, 12 and 22. The enhanced strength allows for a reduction in overall wall thickness in new or replacement components. Extensive research in both service failures and laboratory testing has shown that time-dependent creep damage can develop differently in Grade 91 steel when compared to low alloy steels. Furthermore, the creep strength in Grade 91 can vary by more than a factor of 10 between different heats. This wide variation of creep strength has led to extensive research in understanding the damage mechanisms and progression of damage in this steel. In this study, large cross weld samples were fabricated from thick wall piping in Grade 91 steel using two different heats of material. One weld was fabricated in a ‘damage tolerant’ heat and another weld was fabricated in a ‘damage intolerant’ heat of material. The samples were subjected to a post-weld heat treatment (PWHT) at a temperature of 745°C (1375°F) for 1.50 hours. Hardness maps were collected on the cross-welds in the as-welded and PWHT condition for both weldments. Cross-weld creep test conditions were selected to develop accelerated damage representative of in-service behavior. The test samples were interrupted at multiple stages and nondestructively evaluated (NDE) with advanced phased-array ultrasonic techniques. Samples were developed to variable levels of damage (50% to 100% life fraction) in both weldments. Metallographic sections were extracted at specific locations to validate the NDE findings using light emitting diode, laser and scanning electron microscopy. This research is being used to help validate the level of damage that can be reliably detected using conventional and advanced NDE techniques.

Grade 91 steel has been widely utilized in power plants over the last 20 years. Its specification worldwide has dramatically increased since the acceptance of Code Case 1943 for this material in 1983. Recent evaluation of a combination of ex-service Grade 91 steel components and virgin material has provided a unique opportunity to independently assess the performance of a combination of base metal and weldments. This approach has been grounded in the fundamental objective of linking metallurgical risk factors in Grade 91 steel to the cross-weld creep performance. Establishing critical risk factors in 9Cr steels is regarded as a key consideration in the integration of a meaningful life management strategy for these complex steels. The potential metallurgical risk factors in Grade 91 steel have been fundamentally divided into factors which affect strength, ductility or both. In this study, two heats of ex-service Grade 91 steel which exhibit dramatic differences in strength and ductility have been evaluated in the ex-service condition and re-heat treated to establish a relevant set of strength:ductility variables. This set of variables includes [strength:ductility]: low:low, medium:low, low:high and medium:high. The influence of these strength:ductility variables were investigated for feature type cross-weld creep tests to better evaluate the influence of the initial base material condition on cross-weld creep performance.

Extensive research and development has been undertaken in the UK on MarBN steels. These were first proposed by Professor Fujio Abe from NIMS in Japan. Within the UK, progress has been made towards commercialisation of MarBN-type steel through a series of Government funded industrial collaborative projects (IMPACT, IMPEL, INMAP and IMPULSE). As part of the IMPACT project, which was led by Uniper Technologies, boiler tubes were manufactured from the MarBN steel developed within the project, IBN1, and installed on the reheater drums of Units 2 and 3 of Ratcliffe-on-Soar Power Station. The trial tubes were constructed with small sections of Grade 91 tubing on either side of the IBN1 to allow direct comparison after the service exposure. This is the world’s first use of a MarBN steel on a full-scale operational power plant. In September 2018 the first tube was removed having accumulated 11,727 hours operation and 397 starts. This paper reports microstructural and oxidation analysis, that has been undertaken by Loughborough University as part of IMPULSE project, and outlines future work to be carried out.