The oxide exfoliation is one of the main problems that cause the explosion of superheater or reheater, which threaten the safety of power plant units, but there is no direct test method of the particle concentration of the scales in high temperature steam. Based on the study of ferromagnetic and optical characteristics of scales, the technology and equipment were developed for on-line measurement based on magnetic sensitivity and granularity behavior. Through numerical simulation and dynamic simulation experiments of scale movement under high temperature and high pressure steam, calculating method of the particle concertation of scales in the main steam or reheated steam pipeline was retrieved by local sampling concentration.

The long-term performance of superheater super 304h tube during the normal service of an ultra-supercritical 1000mw thermal power unit was tracked and analyzed, and the metallographic structure and performance of the original tube sample and tubes after 23,400h, 56,000h, 64,000 h, 70,000 h and 80,000 h service were tested. The results show that the tensile strength, yield strength and post-break elongation meet the requirements of ASME SA213 S30432 after long-term service, but the impact toughness decreases significantly. The metallographic organization is composed of the original complete austenite structure and gradually changes to the austenite + twin + second phase precipitates. With the extension of time, the number of second phases of coarseness in the crystal and the crystal boundary increases, and the degree of chain distribution increases. The precipitation phase on the grain boundary is dominated by M 23 C 6 , and there are several mx phases dominated by NbC and densely distributed copper phases in the crystal. The service environment produces a high magnetic equivalent and magnetic induction of the material, the reason is that there are strips of martensite on both sides of the grain boundary, and the number of martensite increases with the length of service.

The spalling of oxide scales at the steam side of superheater and reheater of ultra-supercritical unit is increasingly serious, which threatens the safe and economic operation of the boiler. However, no effective monitoring method is proposed to provide an on-line real-time detection on the spalling of oxide scales. This paper proposes an on-line magnetic non-destructive testing method for oxide granules. The oxide scale-vapor sample from the main steam pipeline forms liquid-solid two-phase flow after the temperature and pressure reduction, and the oxide granules are separated by a separator and piled in the austenitic pipe. According to the difference of the magnetic features of the oxide scales and the austenitic pipe, the oxide granule accumulation height can be detected through the spatial gradient variations of the magnetic induction. The laboratory test results show that the oxide scale accumulation can be accurately calculated according to the spatial gradient changes around the magnetized oxide granules, with the detection error not exceeding 2%.

Ni-38Cr-3.8Al has high hardness and high corrosion resistance with good hot workability, and therefore, it has been applied on various applications. However, in order to expand further application, it is important to understand the high temperature properties. Then, this study focused on the high temperature properties such as thermal phase stability, hardness, tensile property, creep property and hot corrosion resistance. As the result of studies, we found that the thermal phase stability of (γ/α-Cr) lamellar structure and the high temperature properties were strongly influenced by the temperature. Although the high temperature properties, except for creep property, of Ni-38Cr-3.8Al were superior to those of conventional Ni-based superalloys, the properties were dramatically degraded beyond 973 K. This is because the lamellar structure begins to collapse around 973 K due to the thermal stability of the lamellar structure. The hot corrosion resistance of Ni-38Cr-3.8Al was superior to that of conventional Ni-based superalloys, however, the advantage disappeared around 1073 K. These results indicate that Ni-38Cr-3.8Al is capable as a heat resistant material which is required the hot corrosion resistance rather than a heat resistant material with high strength at high temperature.