Search Results for additive manufacturing

The Alloys-by-Design approach, involving large-scale CALPHAD calculations to search a compositional range, has been used to isolate a suitable nickel-based superalloy for additive manufacturing (AM) by optimizing the trade-off between processability and increasing strength. This has been done in response to the limited focus on development of new superalloys designed to overcome the limitations of the AM process, specifically the high defect density of parts made from high-performance alloys. Selected compositions have been made using gas atomization, and laser powder-bed fusion AM trials were performed. The resulting properties were evaluated in the as-processed, heat treated and thermally exposed conditions. The assessment, combined with characterization techniques including scanning electron microscopy and atom probe tomography, rationalizes a temperature capability up to and above 850 °C, and demonstrate the opportunity to develop alloys with properties beyond the current state of the art.

Ni-based superalloy Haynes 282 is a prime candidate for advanced power generation systems due to its superior fabricability, weldability, and high-temperature performance. Additive manufacturing offers potential cost and time savings for gas turbine components. Wire-arc direct energy deposition can create large components but often requires post-processing treatments, such as hot isostatic pressing (HIP), to address porosity. This study explores a low heat-input, high deposition rate GMAW process to achieve fully dense Haynes 282 without HIP. Twenty-one blocks were deposited, varying travel and wire feed speeds. Initial analysis (visual inspection, microstructural examination, and CT) revealed the impact of build parameters on internal porosity and defects. Scanning electron microscopy provided insights into structural heterogeneity and microstructural properties.

Inconel 718 is a nickel-based superalloy known for its excellent combination of high-temperature strength, corrosion resistance, and weldability. Additive Manufacturing (AM) has revolutionized traditional manufacturing processes by enabling the creation of complex and customized components. In this work, three prominent AM techniques: Laser-Based Powder Bed Fusion (PBF), Wire Direct Energy Deposition (DED), and Binder Jet (BJ) processes were explored. A thorough metallographic analysis and comparison of samples was conducted after short-term creep testing originating from each of the three aforementioned techniques in addition to wrought material. Detailed electron microscopy unveiled equiaxed grains in both BJ and wrought samples while PBF samples displayed elongated finer grain structures in the build direction, characteristic of PBF. The DED samples revealed a more bimodal grain distribution with a combination of smaller equiaxed grains accompanied by larger more elongated grains. When assessing the three processes, the average grain size was found to be larger in the BJ samples, while the PBF samples exhibited the most significant variation in grain and sub-grain size. Number density, size, and shape of porosity varied between all three techniques. Post-creep test observations in PBF samples revealed the occurrence of wedge cracking at the failure point, accompanied by a preference for grain boundary creep void formation while BJ samples exhibited grain boundary creep void coalescence and cracking at the failure location. In the DED samples, void formation was minimal however, it seemed to be more prevalent in areas with precipitates. In contrast, the wrought sample showed void formation at the failure site with a preference for areas with primary carbide formation. Despite BJ samples demonstrating similar or even superior rupture life compared to other AM techniques, a noteworthy reduction in rupture ductility was observed. While a coarse, uniform grain size is generally linked to enhanced creep resistance and rupture life, the combination of pre-existing voids along grain boundaries and the formation of new voids is hypothesized to accelerate rapid fracture, resulting in diminished ductility. This research shows careful consideration is needed when selecting an AM technology for high- temperature applications as creep behavior is sensitive to the large microstructural variations AM can introduce.

Additive manufacturing is a groundbreaking manufacturing method that enables nearly lossless processing of high-value materials and produces complex components with a level of flexibility that traditional methods cannot achieve. Wire arc additive manufacturing (WAAM), utilizing a conventional welding process such as gas metal arc welding, is one of the most efficient additive manufacturing technologies. The WAAM process is fully automated and guided by CAD/CAM systems on robotic or CNC welding platforms. This paper explores the fundamental concepts and metallurgical characteristics of WAAM. It focuses primarily on the mechanical properties of printed sample structures made from P91, X20, and alloys 625 and 718 wire feedstock. The study particularly addresses the anisotropy of mechanical properties through both short-term and long-term testing, comparing these results to materials processed using conventional methods.

High gamma prime Ni-based superalloys comprising ≥3.5 % Al are difficult to weld due to high propensity of these materials to weld solidification, heat affected zone liquation, and stress-strain cracking. In this study the root cause analysis of cracking and overview on the developed weldable Ni-based superalloys for repair of turbine engine components manufactured from equiaxed (EA), directionally solidified (DS), and single crystal (SX) materials as well as for 3D AM is provided. It is shown that the problem with the solidification and HAZ liquation cracking of turbine engine components manufactured from EA and DS superalloys was successfully resolved by modification of welding materials with boron and silicon to provide a sufficient amount of eutectic at terminal solidification to promote self-healing of liquation cracks along the weld - base material interface. For crack repair of turbine engine components and 3D AM ductile LW4280, LW7901 and LCT materials were developed. It is shown that LW7901 and LCT welding materials comprising 30 - 32 wt.% Co produced sound welds by GTAW-MA on various SX and DS materials. Welds demonstrated high ductility, desirable combination of strength and oxidation properties for tip repair of turbine blades. Examples of tip repair of turbine blades are provided.

Olefin furnaces contain gravity cast U-bend fittings from Fe-Ni-Cr alloys that can experience premature failures due to a combination of harsh service conditions. The fittings undergo steep temperature variations during startup and shutdown, outer diameter (OD) oxidation from furnace flue gases, and inner diameter (ID) carburization from process fluids. As a result, cracking often occurs along large solidification grain boundaries from interconnected networks of carbides and secondary phases. To address these degradation concerns, Wire Arc Additive Manufacturing (WAAM) is being used to produce a functionally graded fitting that provides increased oxidation, carburization, creep, and thermal fatigue resistance. Three welding wire compositions have been designed based on thermodynamic and kinetic modeling techniques to address the appropriate corrosion resistance and mechanical properties needed in the OD, Core, and ID regions of the U- bend fitting cross-section. A Fe-35Cr-45Ni-0.7Nb solid welding wire is being used for the Core section, and metal-cored welding wires based around this composition with additions of Si or Al are being used for the OD and ID sections, respectively. This study involved weldability evaluation focused on understanding the microstructures and potential additive manufacturing printability challenges associated with graded WAAM structures using these welding wires. To achieve this, Cast Pin Tear Testing (CPTT) was performed to evaluate solidification cracking susceptibility of the welding wires. Additionally, Scheil calculations were performed in Thermo-Calc software to predict solidification microstructures. To validate the results, SEM characterization was conducted on cast buttons of each welding wire to identify phases in the respective microstructures. These unique data will help inform WAAM design parameters needed to produce a Functionally Graded Material (FGM) that improves the lifetime of Fe-Ni-Cr U-bend fittings in olefin furnaces.?

This study investigates a novel approach to addressing the persistent Type IV cracking issue in Grade 91 steel weldments, which has remained problematic despite decades of service history and various mitigation attempts through chemical composition and procedural modifications. Rather than further attempting to prevent heat-affected zone (HAZ) softening, we propose eliminating the vulnerable base metal entirely by replacing critical sections with additively manufactured (AM) weld metal deposits using ASME SFA “B91” consumables. The approach employs weld metal designed for stress-relieved conditions rather than traditional normalizing and tempering treatments. Our findings demonstrate that the reheat cycles during AM buildup do not produce the substantial softening characteristic of Type IV zones, thereby reducing the risk of premature creep failure. The study presents comprehensive properties of the AM-built weld metal after post-weld heat treatment (PWHT), examines factors influencing deposit quality and performance, and explores the practical benefits for procurement and field construction, supported by in-service data and application cases.

The advancement of additive manufacturing (AM) technology has heightened interest in producing components from nickel-based superalloys for high-temperature applications; however, developing high gamma prime (γ’) strengthened alloys suitable for AM at temperatures of 1000°C or higher poses significant challenges due to their “non-weldable” nature. Traditional compositions intended for casting or wrought processes are often unsuitable for AM due to their rapid heating and cooling cycles, leading to performance compromises. This study introduces ABD-1000AM, a novel high gamma prime Ni-based superalloy designed using the Alloys-by-Design computational approach to excel in AM applications at elevated temperatures. Tailored for AM, particularly powder bed fusion, ABD-1000AM demonstrates exceptional processing capability and high-temperature mechanical and environmental performance at 1000°C. The study discusses the alloy design approach, highlighting the optimization of key performance parameters, composition, and process-microstructure-performance relationships to achieve ABD-1000AM’s unique combination of processability and creep resistance. Insights from ABD-1000AM’s development inform future directions for superalloy development in complex AM components.

This study evaluates the elevated temperature mechanical performance of 316H stainless steel produced using directed energy deposition (DED) additive manufacturing (AM) from three separate collaborative research programs focused on understanding how AM variables affect creep performance. By combining these studies, a critical assessment of variables was possible including the DED AM method (laser powder and gas metal arc wire), laser power, sample orientation relative to build orientation, chemical composition, and post-processing heat treatment. Detailed microstructure characterization was used to supplement creep and chemistry results to provide insights into potential mechanistic differences in behavior. The study found that sample orientation was a critical variable in determining lower-bound creep behavior, but that in general the lowest creep strength orientation and the lowest creep ductility orientation were not the same. Heat treatment was also an important variable with as-printed materials showing for specific test conditions improved performance and that underlying substructures formed due to inhomogeneous chemical distributions were not completely removed when using standard wrought solution annealing heat-treatments. The chemistry of the final deposited parts differed from the starting stock and may be an important consideration for long-term performance which is not fully appreciated. Overall, the study found that while all the DED materials tested fell within an expected wrought scatter band of performance, the actual creep performance could vary by an order of magnitude due to the many factors described.

The measurement of damage from high temperature solid particle erosion (HTSPE) can be a lengthy process within the laboratory with many lab-based systems requiring sequential heat and cooling of the test piece to enable mass and/or scar volume measurements to be made ex situ. Over the last few years a new lab-based system has been in development at the National Physical Laboratory which has the ability to measure the mass and volume change of eroded samples in situ without the need to cool the sample. Results have previously been shown demonstrating the in situ mass measurement, more recently the in situ volume measurement capability has been added and used to evaluate the erosion performance of additively manufactured materials. Selective laser melting (SLM) is an advanced manufacturing method which is growing in popularity and application. It offers the ability to manufacture low volume complex parts and has been used in rapid prototyping. As the technique has developed there is increasing interest to take advantage of the ability to manufacture complex parts in one piece, which in some case can be more cost and time effective than traditional manufacturing routes. For all the benefits of SLM there are some constraints on the process, these include porosity and defects in the materials such as ‘kissing bonds’, surface roughness, trapped powder and microstructural variation. These features of the processing route may have implications for component performance such as strength, fatigue resistance wear and erosion. To investigate this further SLM IN718 has been used to evaluate factors such as surface roughness, microstructure and morphology on the erosion performance as measured in situ and compared with conventional produced wrought IN718 material.

This study examines the corrosion resistance of additively manufactured 316L stainless steel (SS) for nuclear applications across three environments: pressurized water reactor primary water (PWR PW), hot concentrated nitric acid, and seawater. Wire-feed laser additive manufacturing (WLAM) specimens showed oxidation behavior similar to wrought 316L SS in PWR PW, though stress corrosion cracking (SCC) susceptibility varied with heat treatment. In nitric acid testing, laser powder bed fusion (L-PBF) specimens demonstrated superior corrosion resistance compared to conventional SS, primarily due to improved intergranular corrosion resistance resulting from cleaner feedstock powder and rapid solidification rates that minimized grain boundary segregation. Laser metal deposition (LMD) repair studies in seawater environments successfully produced dense, crack-free repairs with good metallurgical bonding that matched the substrate’s mechanical properties while maintaining corrosion resistance. These results emphasize the importance of corrosion testing for additively manufactured components and understanding how their unique microstructures affect performance.

The power industry has been faced with continued challenges around decarbonization and additive manufacturing (AM) has recently seen increased use over the last decade. The use of AM has led to significant design changes in components to improve the overall efficiency of gas turbines and more recently, hot-section components have been fabricated using AM nickel-base superalloys, which have shown substantial benefits. This paper will discuss and summarize extensive studies led by EPRI in a novel AM nickel-base superalloy (ABD·900-AM). A comprehensive high temperature creep testing study including >67,000 hours of creep data concluded that ABD-900AM shows improved properties compared to similar ~35% volume fraction gamma prime strengthened nickel-base superalloys fabricated using additive methods. Several different creep mechanisms were identified and various factors influencing high temperature behavior, such as grain size, orientation, processing method, heat treatment, carbide structure, chemistry and porosity were explored. Additional studies on the printability, recyclability of powder, wide range of process parameters and several other factors have also been studied and results are summarized. A summary on the alloy -by-design approach and accelerated material acceptance of ABD-900AM through extensive testing and characterization is further discussed. Numerous field studies and examples of field use cases in ABD-900AM are also evaluated to showcase industry adoption of ABD-900AM.

There is an increased interest in miniature testing to determine material properties. The small punch test is one miniaturized test method that has received much interest and is now being applied to support the design and life assessment of components. This paper presents the results of a test program for a small punch creep test at 650°C of 316L stainless steel produced from additive manufacturing. A major finding is that the deflection rate curve versus time may have multiple minima as opposed to forged 316L with only one minimum. This is believed to be due to microcracking and has direct consequences on the determination of the creep properties that that are based on a single minimum value in the CEN Small Punch Standard. In the paper, aged and nonaged materials are compared, and small punch creep results are also compared with standard uniaxial creep tests. The multiple minima feature means that the approach to determine equivalent stress and strain rate from the minimum deflection rate needs to be modified. Some approaches for this are discussed in the paper. Under the assumption that the multiple minima represent cracking, it opens up opportunities to quantify reduced creep ductility by the small punch test.

Laser additive manufacturing (AM) is being considered by the nuclear industry to manufacture net- shape components for advanced reactors and micro reactors. Part-to-part and vendor-to-vendor variations in part quality, microstructure, and mechanical properties are common for additively manufactured components, attributing to the different processing conditions. This work demonstrates the use of microstructurally graded specimen as a high throughput means to establish the relationship between process-microstructure-creep properties. Through graded specimen manufacturing, multiple microstructures, correlated to the processing conditions, can be produced in a single specimen. The effects of a solution annealing heat treatment on the microstructure and creep properties of AM 316H are investigated in this work. Using digital image correlation (DIC), the creep strain can be calculated in these graded regions, allowing for multiple microstructures to be probed in a single creep test. The solution annealing heat treatment was not sufficient in recrystallization of the large, elongated grains in the AM material; however, it was sufficient in removing the cellular structure commonly found in AM processed alloys creating a network of subgrains in their place. The resulting changes in microstructure and mechanical properties are presented. The heat treatment was found to generally increase the minimum creep rate, reduce the minimum creep rate, and reduce the ductility. Significant amounts of grain boundary carbides and cavitation were observed.

To operate future fusion power plants economically, the fusion community needs structural materials that can last longer and operate at higher temperatures than current materials, as well as better heat-dissipating components and a reliable supply chain for them. Additive manufacturing (AM) of existing reduced activation ferritic/martensitic steels (RAFMS) has the potential to solve these problems, which is why we developed a laser powder bed fusion (LPBF) process for Eurofer97 steel, demonstrating excellent mechanical properties (~30% improved yield strength, ~6300% improved creep rupture life, similar toughness and ductility compared to wrought Eurofer97) and low process scatter (relative standard error for yield, tensile strength and elongation on build plate <1%). The main remaining challenge is the consistent sourcing of quality Eurofer97 powder, but we have shown that this can already be done if the limits on impurity elements are slightly relaxed. Our work lays the groundwork for the manufacture of complex fusion components that can dissipate heat better and have a higher operating temperature thanks to the improved material properties. It also helps plug the current RAFMS supply chain gap, enabling easier component prototyping and small-scale manufacture that can smoothly scale in volume in the future.

Additive manufacturing is being considered for pressure boundary applications for power plant service by ASME Boiler and Pressure Vessel Code and regulators. Both existing and new plants could benefit from the reduced lead times, design flexibility, and part consolidation possible with additive manufacturing. Various ASME code committees are working towards rules and guidance for use of additive manufacturing. To further the industry's understanding, this research program was undertaken to evaluate the properties of wire arc additive manufactured 316L stainless steel. This study included microstructural characterization, chemical composition testing, mechanical testing, and nondestructive evaluation of multiple large (1600-pound (700 kg)) 316LSi stainless steel valve bodies produced using the gas metal arc directed energy deposition process followed by solution annealing. The results showed the tensile behavior over a range of temperatures was comparable to wrought material. No variation in tensile behavior was observed with change in tensile sample orientation relative to the build direction. Room temperature Charpy V-notch absorbed energy toughness was comparable to wrought material. Large grain sizes were observed in the metallographic samples, indicating that lowering the solution anneal temperature may be worthwhile. The results of surface and volumetric examination were acceptable when compared to forged material acceptance criteria. Together these results suggest that GMA-DED can produce acceptable materials properties comparable to forged materials requirements.

This study investigates the steam oxidation behavior of Alloy 699 XA, a material containing 30 wt.% chromium and 2 wt.% aluminum that forms protective oxide scales in low-oxygen conditions. The research compares four variants of the alloy: conventional bulk material, a laser powder bed fusion (LPBF) additively manufactured version, and two modified compositions. The modified versions include MAC-UN-699-G, optimized for gamma-prime precipitation, and MAC-ISIN-699, which underwent in-situ internal nitridation during powder atomization. All variants were subjected to steam oxidation testing at 750°C and 950°C for up to 5000 hours, with interim analyses conducted at 2000 hours. The post-exposure analysis employed X-ray diffraction (XRD) to identify phase development and scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS) to examine surface morphology, cross-sectional microstructure, and chemical composition. This study addresses a significant knowledge gap regarding the steam oxidation behavior of 699 XA alloy, particularly in its additively manufactured state.

Alloy 718 is one of the most widely used for aircraft engine and gas turbine components requiring oxidation and corrosion resistance as well as strength at elevated temperatures. Alloy 718 has been produced in both wrought and cast forms, but metal injection molding and metal-based additive manufacturing (AM) technologies have the potential to create a three-dimensional component. Their mechanical properties are highly dependent on the types of powder processing, but the relationship between microstructures and properties has not been clarified. In this study, the mechanical properties of Alloy 718 manufactured by AM are compared to cast and wrought properties. The electron beam melting processed specimens with strong anisotropy showed higher yield strength, which can be explained by critical resolved shear stress. In addition, the creep deformation showed a complicated behavior which was different from that of wrought alloy. Such abnormal behavior was characterized by γ-channel dislocation activity.

This study explores the expanded applications of Alloy J513, a high-performance material traditionally used in cast engine valvetrain components, for powder metallurgy and surface cladding applications. While already recognized for its superior heat and wear resistance at a lower cost compared to cobalt-based hardfacing materials, J513 demonstrates additional advantages in powder metallurgy applications due to its ability to achieve desired powder characteristics through atomization without requiring post-atomization annealing. Through experimental investigation based on fundamental metallurgical principles and cladding engineering processes, the presented research demonstrates J513’s exceptional weldability and favorable weldment structure compared to conventional cobalt-based alloys. The study establishes crucial relationships between weldment behavior and unit energy input, providing valuable insights for advanced cladding techniques while highlighting J513’s potential as a sustainable alternative to traditional nickel- and cobalt-based alloys in various manufacturing processes, including surface overlay and additive manufacturing.

At present there is no recognized standard test method that can be used for the measurement of the tensile properties of additively manufactured lattice structures. The aim of this work was to develop and validate a methodology that would enable this material property to be measured for these geometrically and microstructurally complex material structures. A novel test piece has been designed and trialed to enable lattice struts and substructures to be manufactured and tested in standard bench top universal testing machines and in small scale in-situ SEM loading jigs (not reported in this paper). In conjunction with the mechanical tests, a finite element (FEA) modelling approach has been used to help cross validate the methodology and results, and to enable larger lattice structures to be modelled with confidence. The specimen design and testing approach developed, is described and the results reviewed for AlSi10Mg.