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Gas tungsten arc welding
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Proceedings Papers
AM-EPRI2024, Advances in Materials, Manufacturing, and Repair for Power Plants: Proceedings from the Tenth International Conference, 50-61, February 25–28, 2025,
Abstract
View Papertitled, Development and Commercialization of Adaptive Feedback Welding Technology for Fabrication and Repair Applications
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for content titled, Development and Commercialization of Adaptive Feedback Welding Technology for Fabrication and Repair Applications
There is a growing need to automate the gas tungsten arc welding process for fabrication and repair of nuclear components due to an increasing shortage of experienced welders. Therefore, a collaborative effort has been performed in this study to develop a fully autonomous gas tungsten arc welding system with adaptive capabilities. The system employs the application of two neural networks that have been presented in. The first utilizes a vision based convolutional neural network to perform real time control of the filler wire entry position into the weld pool. The second predicts optimal weld parameters and torch positioning for each weld pass deposited within a multi-pass groove. A commercialization path for the technology is in-progress, with the artificial intelligent algorithms currently being incorporated and tested on commercially available equipment.
Proceedings Papers
Pablo Andrés Gómez Flórez, Alejandro Toro Betancur, John Edison Morales Galeano, Jeisson Mejía Velásquez
AM-EPRI2024, Advances in Materials, Manufacturing, and Repair for Power Plants: Proceedings from the Tenth International Conference, 247-258, February 25–28, 2025,
Abstract
View Papertitled, PAW and GTAW Welding Repair of HP/IP and Generator Rotors of a Steam Turbine for Electric Power Generation
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for content titled, PAW and GTAW Welding Repair of HP/IP and Generator Rotors of a Steam Turbine for Electric Power Generation
This work describes the repair procedure conducted on the High Pressure/Intermediate Pressure (HP/IP) and generator rotors of a 180 MW steam turbine General Electric (GE) - STAG207FA type D11 installed at La Sierra Thermoelectric Power Plant in Puerto Nare, Colombia. A lubricant supply failure at base load caused severe adhesive damage to the shafts in the bearing support areas and a permanent 3.5 mm bow at the HP/IP rotor mid span section, which required a complex intervention. The repair process began with the identification of the rotors manufacturing material through in-situ metallographic replicas, handheld XRF analysis and surface hardness measurements. Volumetric manual Gas Tungsten Arc Welding (GTAW) welding reconstruction of cracked areas followed by a surface overlay using GTAW and Plasma Arc Welding (PAW) welding processes were applied with a modular mechanized system, where a stress relief treatment through vibration was implemented with the help of computational simulations carried out to determine the fundamental frequencies of the rotors. Geometric correction of the HP/IP rotor mid span section was achieved thanks to the excitation of the rotor at some fundamental frequencies defined by the dynamic modeling and the use of heat treatment blankets at specific locations as well. Finally, after machining and polishing procedures, the power unit resumed operation eleven months after the failure and remains in service to the present date.
Proceedings Papers
AM-EPRI2024, Advances in Materials, Manufacturing, and Repair for Power Plants: Proceedings from the Tenth International Conference, 573-581, February 25–28, 2025,
Abstract
View Papertitled, Assessment of Super Duplex Stainless Steel Welding using Hyper Duplex Filler Metal: Microstructure and Corrosion Performance
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for content titled, Assessment of Super Duplex Stainless Steel Welding using Hyper Duplex Filler Metal: Microstructure and Corrosion Performance
Super Duplex stainless steels (SDSS) are alloys based on the Fe-Cr-Ni-N system. The chemical composition is tailored to achieve a balanced microstructure of 50% ferrite and 50% austenite. Hyper Duplex Stainless Steels (HDSS) are also duplex materials distinguished by their remarkable yield strength (≥700 MPa) and corrosion resistance (PREN>48). They have been developed as an alternative to the well-established SDSS when superior mechanical and corrosion performance is required. This enhanced performance is attributed to alloying additions, primarily Cr, Mo, and N. In this study, a comparison is conducted between filler metals of SDSS and HDSS for the root welding of SDSS plates. The gas tungsten arc welding (GTAW) process was used to carry out root welding passes and Gas Metal Arc Welding (GMAW) for filling passes on SDSS substrates arranged in a V groove to simulate a repair scenario. The heat input was controlled in both processes, keeping it below 2.0 kJ/mm in the GTAW and 1.2 kJ/mm in the GMAW. GTAW with constant current was used and the parameters achieved producing full penetration welds with SDSS and HDSS. In this case, Nitrogen was used as backing gas to avoid oxidation of the root. Thus, a special GMAW-Pulsed version was applied to achieve good wettability and defect-free joints. ASTM G48 tests were performed to evaluate the corrosion resistance through Critical Pitting Testing (CPT) analysis on the root pass, microstructural analysis via optical microscopy, and impact toughness. Consequently, a comprehensive examination of the welded joints outlines manufacturing conditions, limitations, and the applications of SDSS and HDSS filler metals.
Proceedings Papers
AM-EPRI2024, Advances in Materials, Manufacturing, and Repair for Power Plants: Proceedings from the Tenth International Conference, 650-661, February 25–28, 2025,
Abstract
View Papertitled, The Development of Weldable Nickel-Based Superalloys and Technologies for Repair and Additive Manufacturing of Turbine Engine Components
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for content titled, The Development of Weldable Nickel-Based Superalloys and Technologies for Repair and Additive Manufacturing of Turbine Engine Components
High gamma prime Ni-based superalloys comprising ≥3.5 % Al are difficult to weld due to high propensity of these materials to weld solidification, heat affected zone liquation, and stress-strain cracking. In this study the root cause analysis of cracking and overview on the developed weldable Ni-based superalloys for repair of turbine engine components manufactured from equiaxed (EA), directionally solidified (DS), and single crystal (SX) materials as well as for 3D AM is provided. It is shown that the problem with the solidification and HAZ liquation cracking of turbine engine components manufactured from EA and DS superalloys was successfully resolved by modification of welding materials with boron and silicon to provide a sufficient amount of eutectic at terminal solidification to promote self-healing of liquation cracks along the weld - base material interface. For crack repair of turbine engine components and 3D AM ductile LW4280, LW7901 and LCT materials were developed. It is shown that LW7901 and LCT welding materials comprising 30 - 32 wt.% Co produced sound welds by GTAW-MA on various SX and DS materials. Welds demonstrated high ductility, desirable combination of strength and oxidation properties for tip repair of turbine blades. Examples of tip repair of turbine blades are provided.
Proceedings Papers
AM-EPRI2024, Advances in Materials, Manufacturing, and Repair for Power Plants: Proceedings from the Tenth International Conference, 843-854, February 25–28, 2025,
Abstract
View Papertitled, Sigma Embrittlement Evaluation Test for Dissimilar Welding Between F6NM and FXM-19
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for content titled, Sigma Embrittlement Evaluation Test for Dissimilar Welding Between F6NM and FXM-19
In dissimilar welds between martensitic stainless steel F6NM and nitrogen-strengthened austenitic stainless steel FXM-19, type 209 austenitic welding consumables are used to align with the mechanical properties and chemical composition of FXM-19, with F6NM welds requiring post-weld heat treatment (PWHT) to restore ductility and toughness, raising concerns about sigma embrittlement in ER209 butter welds. This study investigated the mechanical properties and microstructure of F6NM+FXM-19 dissimilar welds, finding no detrimental sigma phase formation in the butter (PWHT) and groove weld metal (as welded) across various welding processes, indicating no sigma phase transformation due to PWHT. Submerged arc welding (SAW) and gas tungsten arc welding (GTAW) demonstrated good mechanical properties, while Gas Metal Arc Welding with 100% Ar gas shield (GMAW 100% Ar) could not be properly evaluated due to weld defects. SAW and GTAW were deemed suitable for this dissimilar weld joint, with several welding processes providing acceptable results using ER209 filler material for fabricating pressure vessels requiring F6NM to XM-19 joints.
Proceedings Papers
AM-EPRI2024, Advances in Materials, Manufacturing, and Repair for Power Plants: Proceedings from the Tenth International Conference, 855-860, February 25–28, 2025,
Abstract
View Papertitled, Weld Process Effects on Fatigue Performance in the Repair of Coke Drums
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for content titled, Weld Process Effects on Fatigue Performance in the Repair of Coke Drums
Coke drums experience failures in through-wall cracking throughout their operating life, resulting from low cycle fatigue. Coke drums are typically fabricated from Chrome Moly (CrMo) steels. This study was performed on P4 (1.25Cr-0.5Mo) base material using ER70S-B2L and Alloy 625 (ERNiCrMo-3) filler materials. Specimens were welded with the temper-bead/controlled deposition welding technique. The weld processes used were HP-GTAW, GMAW and SMAW. The fatigue performance, HAZ hardness and toughness of the weld samples was evaluated. The HP-GTAW welds exhibited an order of magnitude improvement in fatigue performance when compared to the other weld processes using ER70S-B2L filler material. The HP-GTAW welds also exhibited improved HAZ hardness and toughness when compared to the other weld processes. This presentation will introduce the HP-GTAW process, its features, and benefits and where it is applied in Coke drum repair welding. Comparative test results of the different weld processes for fatigue performance, HAZ tempering, and toughness will also be presented.
Proceedings Papers
AM-EPRI2024, Advances in Materials, Manufacturing, and Repair for Power Plants: Proceedings from the Tenth International Conference, 1008-1019, February 25–28, 2025,
Abstract
View Papertitled, Demonstration of Thick-Section Welding of Haynes 282 to Steel
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for content titled, Demonstration of Thick-Section Welding of Haynes 282 to Steel
This study addresses the welding challenges encountered when joining Haynes 282, a heat-resistant superalloy, to 3.5NiCrMoV high-strength low alloy steel (HSLA) for advanced power plant applications, particularly in thick-section components like rotors. The project demonstrated successful thick-section dissimilar metal welding up to 76 mm (3 in.) using two techniques: keyhole tungsten inert gas welding and conventional gas tungsten arc welding with Haynes 282 filler metal. Various groove weld geometries were evaluated, supported by computational weld modeling to predict and minimize weld distortion. The results validate these welding approaches for critical power plant components requiring both high-temperature performance and cost-effectiveness.
Proceedings Papers
AM-EPRI2019, 2019 Joint EPRI – 123HiMAT International Conference on Advances in High-Temperature Materials, 1060-1068, October 21–24, 2019,
Abstract
View Papertitled, Weld Solidification Behavior and Performance of Nickel-Base Superalloy GH750 for Use in 700 °C Advanced Ultra-Supercritical Boiler
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for content titled, Weld Solidification Behavior and Performance of Nickel-Base Superalloy GH750 for Use in 700 °C Advanced Ultra-Supercritical Boiler
A new nickel-base superalloy GH750 has been developed as boiler tube of advanced ultrasupercritical (A-USC) power plants at temperatures about and above 750°C in China. This paper researched the weld solidification of GH750 filler metal, microstructure development and property of GH750 welded joint by gas tungsten arc weld. Liquid fraction and liquid composition variation under non-equilibrium state were calculated by thermo-dynamic calculation. The weld microstructure and the composition in the dendrite core and interdendritic region were analyzed by SEM(EDX) in detail. The investigated results show that there is an obvious segregation of precipitation-strengthening elements during the weld solidification. Titanium and Niobium are the major segregation elements and segregates in the interdendritic region. It was found that the changing tendency of the elements’ segregation distribution during the solidification of GH750 deposit metal is agree with the thermodynamic calculation results. Till to 3,000hrs’ long exposure at 750°C and 800°C, in comparison with the region of dendrite core of solidification microstructure, not only the coarsening and the accumulation of γʹ particles are remarkable in the interdendritic region, but also the small quantity of the blocky and needle like η phases from. The preliminary experimental results indicate that the weakening effect of creep-rupture property of the welded joint is not serious compared with GH750 itself.
Proceedings Papers
AM-EPRI2019, 2019 Joint EPRI – 123HiMAT International Conference on Advances in High-Temperature Materials, 1069-1078, October 21–24, 2019,
Abstract
View Papertitled, Study on GTAW Welded Joint of Nimonic 263 Alloy after Aging at 750℃ for Gas Turbine Transition Pieces
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for content titled, Study on GTAW Welded Joint of Nimonic 263 Alloy after Aging at 750℃ for Gas Turbine Transition Pieces
Nimonic 263 alloy was selected for gas turbine combustor transition piece due to its excellent high temperature mechanical performance. In present work, Nimonic 263 alloy plate with thickness of 5mm was welded using 263 filler metal by GTAW, then post weld heat treatment of 800℃/8h/air cool was carried out. The hardness and impact toughness of welded joints were measured, and the microstructure evolution after aging at 750℃ for 3000h was investigated by scanning electron microscopy(SEM). The results show that, during the aging process, the hardness of weld metal increases firstly and then decreases. The impact toughness decreases significantly at first and then increase. Furthermore, some fluctuations can be detected in hardness and impact toughness after long-term thermal exposure. The significant decrease in the impact toughness of the aged welded joints mainly results from the precipitation of η phase around grain boundary and intergranular MC phase. The hardness of weld metal increases due to the precipitation of more carbides and γ′ phase after 1000h aging, then decreases owing to the growth of γ′ phase after 3000h aging.
Proceedings Papers
AM-EPRI2019, 2019 Joint EPRI – 123HiMAT International Conference on Advances in High-Temperature Materials, 1109-1122, October 21–24, 2019,
Abstract
View Papertitled, Characterization of Suitable Fillers for Butt Weld of Creep Aged X20 and Virgin P91 Pipes
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for content titled, Characterization of Suitable Fillers for Butt Weld of Creep Aged X20 and Virgin P91 Pipes
Components such as tubes, pipes and headers used in power generation plants are operated in a creep regime and have a finite life. During partial replacement, creep exhausted materials are often welded to virgin materials with superior properties. The aim of this study was to identify a suitable weld filler material to join creep aged X20CrMoV12-1 to a virgin P91 (X10CrMoVNbV9-1) steel. Two dissimilar joints were welded using the gas tungsten arc welding (GTAW) process for the root passes, and manual metal arc (MMA) welding for filling and capping. The X20 and the P91 fillers were selected for joining the pipes. The samples were further heat treated at 755°C to stress relief the samples. Microstructural evolution and mechanical properties of the weld metals were evaluated. The average hardness of X20 weld metal (264 HV10) was higher than the hardness measurement of P91 weld metal (206 HV10). The difference in hardness was attributed to the high carbon content in X20 material. The characterisation results revealed that the use of either X20 or P91 weld filler for a butt weld of creep aged X20 and virgin P91 pipes material does not have a distinct effect on the creep life and creep crack propagation mechanism. Both weld fillers (X20 and P91) are deemed to be suitable because limited interdiffusion (<10 μm) of chromium and carbon at the dissimilar weld interface was observed across the fusion line. The presence of a carbon ‘denuded’ zone was limited to <10 μm in width, based on the results from local measurements of the precipitate phase fractions using image analysis and from elemental analysis using EDS. However the nanoindentation hardness measurements across the fusion line could not detect any ‘soft’ zone at the dissimilar weld interface. The effect of the minute denuded zone was also not evident when the samples were subjected to nanoindentation hardness testing, tensile mechanical testing, Small Punch Creep Test (SPCT) and cross weld uniaxial creep testing.
Proceedings Papers
AM-EPRI2016, Advances in Materials Technology for Fossil Power Plants: Proceedings from the Eighth International Conference, 702-713, October 11–14, 2016,
Abstract
View Papertitled, Tensile, Creep and Microstructural Behavior of Welded Cast Haynes 282 Alloy for A-USC Steam Turbine Casing Applications
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for content titled, Tensile, Creep and Microstructural Behavior of Welded Cast Haynes 282 Alloy for A-USC Steam Turbine Casing Applications
Haynes 282 alloy is a relatively new Ni-based superalloy that is being considered for advanced ultrasupercritical (A-USC) steam turbine casings for steam temperatures up to 760°C. Weld properties are important for the turbine casing application, so block ingots of Haynes 282 alloy were cast for properties studies. Good, sound welds were produced using Haynes 282 weld-wire and a hot gas-tungsten-arc welding method, and tensile and creep-rupture properties were measured on cross-weld specimens. In the fully heat-treated condition (solution annealed + aged), the tensile properties of the welded specimens compare well with as-cast material. In the fully heat-treated condition the creep-rupture life and ductility at 750°C/250MPa and 800°C/200MPa of the cross-weld specimens are similar to the as-cast base metal, and repeat creep tests show even longer rupture life for the welds. However, without heat-treatment or with only the precipitate age-hardening heat-treatment, the welds have only about half the rupture life and much lower creep ductility than the as-cast base metal. These good properties of weldments are positive results for advancing the use of cast Haynes 282 alloy for the A-USC steam turbine casing application.
Proceedings Papers
AM-EPRI2013, Advances in Materials Technology for Fossil Power Plants: Proceedings from the Seventh International Conference, 573-585, October 22–25, 2013,
Abstract
View Papertitled, Phase Transformations and Microstructure in Gas Tungsten Arc Welds of Grade 23 Steel Tubing
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for content titled, Phase Transformations and Microstructure in Gas Tungsten Arc Welds of Grade 23 Steel Tubing
The objective of this study was to determine the typical range of weld metal cooling rates and phase transformations during multipass gas-tungsten arc (GTA) welding of Grade 23 (SA-213 T23) tubing, and to correlate these to the microstructure and hardness in the weld metal and heat affected zone (HAZ). The effect of microstructure and hardness on the potential susceptibility to cracking was evaluated. Multipass GTA girth welds in Grade 23 tubes with outside diameter of 2 in. and wall thicknesses of 0.185 in. and 0.331 in. were produced using Grade 23 filler wire and welding heat input between 18.5 and 38 kJ/in. The weld metal cooling histories were acquired by plunging type C thermocouples in the weld pool. The weld metal phase transformations were determined with the technique for single sensor differential thermal analysis (SS DTA). The microstructure in the as-welded and re-heated weld passes was characterized using light optical microscopy and hardness mapping. Microstructures with hardness between 416 and 350 HV 0.1 were found in the thick wall welds, which indicated potential susceptibility to hydrogen induced cracking (HIC) caused by hydrogen absorption during welding and to stress corrosion cracking (SSC) during acid cleaning and service.
Proceedings Papers
AM-EPRI2013, Advances in Materials Technology for Fossil Power Plants: Proceedings from the Seventh International Conference, 903-913, October 22–25, 2013,
Abstract
View Papertitled, Evaluation of Creep Rupture Strength in Ni-Based Alloy Weldments for an Advanced USC Boiler
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for content titled, Evaluation of Creep Rupture Strength in Ni-Based Alloy Weldments for an Advanced USC Boiler
A Japanese national project has been undertaken since Aug. 2008 with the objective of developing an advanced ultra-supercritical power plant (A-USC) with a steam temperature of 700°C. Fe-Ni and Ni-based alloys, namely HR6W, HR35, Alloy617, Alloy740, Alloy263 and Alloy141, were taken as candidate materials for piping and superheater/reheater tubes in an A-USC boiler. Weldments of these alloys were manufactured by GTAW, after which long term creep rupture tests were conducted at 700°C, 750°C and 800°C. Weldments of HR6W, HR35 and Alloy617 showed similar creep strength as compared with these base metals. Weldments of Alloy740 tended to fail in the HAZ, and it is considered that voids and cracks preferentially formed in the small precipitation zone along the grain boundary in the HAZ. The creep strength of Alloy263 in weldments exhibited the highest level among all the alloys, although HAZ failure occurred in the low stress test condition. A weld strength reduction factor will be needed to avoid HAZ failure in Alloy740 and Alloy263. Also, to prevent premature failure in weld metal, optimization of the chemical composition of weld filler materials will be required.
Proceedings Papers
AM-EPRI2013, Advances in Materials Technology for Fossil Power Plants: Proceedings from the Seventh International Conference, 1016-1024, October 22–25, 2013,
Abstract
View Papertitled, Effect of Non-Standard Heat Treatments on Creep Performance of Creep-Strength Enhanced Ferritic (CSEF) Steel Weldments
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for content titled, Effect of Non-Standard Heat Treatments on Creep Performance of Creep-Strength Enhanced Ferritic (CSEF) Steel Weldments
This paper summarizes recent efforts to improve creep performance in Grade 91 (Mod. 9Cr-1Mo, ASTM A387) steel weldments via non-standard heat treatments prior to welding. Such heat treatments offer a potential solution for minimizing Type IV failures in creep strength enhanced ferritic (CSEF) steels. A lower temperature tempering (LTT, 650°C) of the 9Cr steels prior to gas tungsten arc welding (GTAW) resulted in improved creep-rupture life at 650°C compared to the samples tempered at a standard condition (HTT, 760°C) before welding. From detailed characterization of precipitation kinetics in the heat affected zone, it was hypothesized that M 23 C 6 carbides in the fine-grain heat-affected zone (FGHAZ) in the LTT sample were fully dissolved, resulting in re-precipitation of strengthening carbides during post weld heat treatment (PWHT). This was not the case in the HTT sample since M 23 C 6 in the FGHAZ was only partially dissolved prior to welding, which caused coarsening of existing M 23 C 6 after PWHT and premature creep failure in the FGHAZ. However, it was also found that the LTT raised the ductile-brittle transition temperature above room temperature (RT). Two different thermo-mechanical treatments (TMTs); two-step tempering and aus-forging/aus-aging, of the modified 9Cr-1Mo steels were attempted, in order to control the balance between creep properties and RT ductility, through control of precipitation kinetics of the M 23 C 6 carbides and/or MX carbo-nitrides. The hardness map of the TMT samples after GTAW and PWHT were evaluated.
Proceedings Papers
AM-EPRI2013, Advances in Materials Technology for Fossil Power Plants: Proceedings from the Seventh International Conference, 1047-1058, October 22–25, 2013,
Abstract
View Papertitled, Development of Welding and Fabrication Technologies in Advanced USC Boiler
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for content titled, Development of Welding and Fabrication Technologies in Advanced USC Boiler
Welding processes and fabrication techniques have been studied in the development of Advanced USC boilers. Advanced 9Cr steels, Fe-Ni alloy (HR6W) and Nickel base alloys (HR35, Alloy 617, Alloy 263, Alloy 740 and Alloy 740H) have been selected as candidate materials for the boiler. The weld joints of these alloys were prepared from plates, small diameter tubes and large pipes, and welding procedure tests were performed. In this study, TIG and SMAW were applied. Both welding process produced good weld joints, and they showed good results in bending tests, tensile tests and the Charpy impact test. To select the annealing conditions for stress relief, stress relaxation tests and hardness tests were conducted on the weld joints after various heat treatments. The microstructure was also evaluated by SEM and TEM. Creep rupture tests are being performed for the weld joints with and without heat treatment. The maximum creep rupture tests are expected to take over 100,000 hours. In the study of fabrication techniques, hot bending tests by high frequency induction heating for large pipes and cold/hot bending tests for small diameter tubes were established. After the bending tests, mechanical property tests such as tensile tests, impact tests and creep rupture tests were conducted. The effect of pre-strain on creep strength was studied to take the creep test results after bending into consideration. The creep rupture test will be continued for specimens from weld joints and bending pipes to show their long term reliability.
Proceedings Papers
AM-EPRI2007, Advances in Materials Technology for Fossil Power Plants: Proceedings from the Fifth International Conference, 818-829, October 3–5, 2007,
Abstract
View Papertitled, Weldability Investigation of Inconel Alloy 740 for Ultrasupercritical Boiler Applications
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for content titled, Weldability Investigation of Inconel Alloy 740 for Ultrasupercritical Boiler Applications
Inconel alloy 740, a precipitation-hardenable nickel-chromium-cobalt alloy with niobium addition, has emerged as a leading candidate material for ultra-supercritical (USC) boilers due to its superior stress rupture strength and corrosion resistance at operating temperatures near 760°C. While derived from Nimonic alloy 263, alloy 740's unique chemistry necessitates comprehensive weldability studies to address potential challenges including heat-affected zone liquation cracking, ductility-dip cracking, and post-weld heat treatment cracking. This ongoing investigation examines the alloy's weldability characteristics through material characterization studies comparing its cracking sensitivity to established aerospace alloys like Waspalloy and Inconel alloy 718. The research applies aerospace industry expertise to boiler applications requiring sections up to three inches thick, with gas tungsten arc welding and pulsed gas metal arc welding identified as the most promising processes for producing sound, crack-free welds.
Proceedings Papers
AM-EPRI2004, Advances in Materials Technology for Fossil Power Plants: Proceedings from the Fourth International Conference, 337-356, October 25–28, 2004,
Abstract
View Papertitled, Weldability and Long-Term Corrosion Behavior of Fe-Al-Cr Alloys in Oxidizing/Sulfidizing Environments
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for content titled, Weldability and Long-Term Corrosion Behavior of Fe-Al-Cr Alloys in Oxidizing/Sulfidizing Environments
Coal burning power companies are currently considering FeAlCr weld overlay claddings for corrosion protection of waterwall boiler tubes located in their furnaces. Previous studies have shown that these FeAlCr coatings exhibit excellent high-temperature corrosion resistance in several types of low NOx environments. In the present study, the susceptibility of FeAlCr weld overlay claddings to hydrogen cracking was evaluated using a gas-tungsten arc welding (GTAW) process. Microsegregation of alloying elements was determined for the FeAlCr welds and compared to a currently used Ni-based superalloy. Long-term gaseous corrosion testing of select weld overlays was conducted along with the Ni-based superalloy in a gaseous oxidizing/sulfidizing corrosion environment at 500°C. The sample weight gains were used along with analysis of the corrosion scale morphologies to determine the corrosion resistance of the coatings. It was found that although there were slight differences in the corrosion behavior of the selected FeAlCr weld coatings, all FeAlCr based alloys exhibited superior corrosion resistance to the Ni-based superalloy during exposures up to 2000 hours.
Proceedings Papers
AM-EPRI2004, Advances in Materials Technology for Fossil Power Plants: Proceedings from the Fourth International Conference, 987-998, October 25–28, 2004,
Abstract
View Papertitled, Suppression of Type IV Failure in High-B Low-N 9Cr-3W-3Co-NbV Steel Welded Joint
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for content titled, Suppression of Type IV Failure in High-B Low-N 9Cr-3W-3Co-NbV Steel Welded Joint
This study investigated the creep rupture strength and microstructure evolution in welded joints of high-boron, low-nitrogen 9Cr steels developed by NIMS. The welds were fabricated using the GTAW process and Inconel-type filler metal on steel plates with varying boron content (47-180 ppm). Creep rupture tests were conducted at 923K for up to 10,000 hours. Despite their higher boron content, these steels exhibited good weldability. Welded joints of the boron steel displayed superior creep properties compared to conventional high-chromium ferritic steel welds like P92 and P122. Notably, no Type IV failures were observed during creep testing. Welding introduced a large-grained microstructure in the heat-affected zone (HAZ) heated to the austenite transformation temperature (Ac3 HAZ). This contrasts with the grain refinement observed in the same region of conventional heat-resistant steel welds. Interestingly, the grain size in this large microstructure was nearly identical to that of the base metal. Analysis of the simulated Ac3 HAZ revealed crystal orientation distributions almost identical to those of the original specimen. This suggests a regeneration of the original austenite structure during the alpha-to-gamma phase transformation. Simulated Ac3 HAZ structures of the boron steel achieved creep life nearly equivalent to the base metal. The suppression of Type IV failure and improved creep resistance in welded joints of the boron steels are likely attributed to the large-grained HAZ microstructures and stabilization of M 23 C 6 precipitates. The optimal boron content for achieving the best creep resistance in welded joints appears to lie between 90 and 130 ppm, combined with minimized nitrogen content.