Gas turbine efficiency is typically limited by the maximum allowable temperature for components at the inlet side and in the hot gas flow. Refractory alloys and SiC/SiC ceramic-matrix composites (CMCs) are promising candidates for advancing operating temperatures beyond those of Ni-based alloys (>1200 °C). Refractory alloys are more suitable than SiC/SiC CMCs for dynamic components, due to the latter's low toughness and ductility. However, it is well known that refractory alloys suffer from poor oxidation behavior under service lifetimes and conditions, leading to embrittlement concerns. The ARPA-E ULTIMATE program has set out to combine new alloys with advanced coatings to mitigate oxidation/embrittlement effects, while increasing the mechanical performance benefits of refractory materials. Low oxygen (inert gas) or vacuum systems are needed to assess high temperature mechanical performance of developed alloys. To investigate the environmental sensitivity of candidate alloys and develop high temperature testing capabilities, four argon tensile frames were upgraded as well as a single vacuum system at Oak Ridge National Laboratory. Digital image correlation was incorporated into the vacuum frame allowing for surface strain determination and refined insight into thermomechanical response. Creep testing was performed at 1300 °C on two alloys, C-103 and MHC in vacuum and high purity argon environments. The Mo-based alloy showed less sensitivity to oxygen, indicating that testing in well-controlled argon environments may be suitable. The C-103 alloy demonstrated a stronger sensitivity to oxygen in the well-controlled argon environment, illustrating the need for the developed vacuum testing capabilities. “Small” 25 mm and “large” 76 mm MHC specimens showed comparable results in terms of strain rate during creep testing and ultimate tensile strength during tensile testing, suggesting the viability of smaller geometries that use less material of advanced developmental alloys.

The power industry has been faced with continued challenges around decarbonization and additive manufacturing (AM) has recently seen increased use over the last decade. The use of AM has led to significant design changes in components to improve the overall efficiency of gas turbines and more recently, hot-section components have been fabricated using AM nickel-base superalloys, which have shown substantial benefits. This paper will discuss and summarize extensive studies led by EPRI in a novel AM nickel-base superalloy (ABD·900-AM). A comprehensive high temperature creep testing study including >67,000 hours of creep data concluded that ABD-900AM shows improved properties compared to similar ~35% volume fraction gamma prime strengthened nickel-base superalloys fabricated using additive methods. Several different creep mechanisms were identified and various factors influencing high temperature behavior, such as grain size, orientation, processing method, heat treatment, carbide structure, chemistry and porosity were explored. Additional studies on the printability, recyclability of powder, wide range of process parameters and several other factors have also been studied and results are summarized. A summary on the alloy -by-design approach and accelerated material acceptance of ABD-900AM through extensive testing and characterization is further discussed. Numerous field studies and examples of field use cases in ABD-900AM are also evaluated to showcase industry adoption of ABD-900AM.

This study investigates how temperature affects the plasticity and thermal creep behavior of 347H stainless steel under uniaxial tension. The research combined experimental testing with advanced computational modeling. Two types of experiments were conducted: uniaxial tensile tests at temperatures from 100°C to 750°C using strain rates of ~10⁻⁴ s⁻¹, and creep tests at temperatures between 600°C and 750°C under various stress levels. These experimental results were used to develop and validate a new integrated mechanistic model that can predict material behavior under any loading condition while accounting for both stress and temperature effects. The model was implemented using a polycrystalline microstructure simulation framework based on elasto-viscoplastic Fast Fourier Transform (EVPFFT). It incorporates three key deformation mechanisms: thermally activated dislocation glide, dislocation climb, and vacancy diffusional creep. The model accounts for internal stress distribution within single crystals and considers how precipitates and solute atoms (both interstitial and substitutional) affect dislocation movement. After validation against experimental data, the model was used to generate Ashby-Weertman deformation mechanism maps for 347H steel, providing new insights into how microstructure influences the activation of different creep mechanisms.

The Advanced Materials and Manufacturing Technologies (AMMT) program is aiming at the accelerated incorporation of new materials and manufacturing technologies into nuclear-related systems. Complex Ni-based components fabricated by laser powder bed fusion (LPBF) could enable operating temperatures at T > 700°C in aggressive environments such as molten salts or liquid metals. However, available mechanical properties data relevant to material qualification remains limited, in particular for Ni-based alloys routinely fabricated by LPBF such as IN718 (Ni- 19Cr-18Fe-5Nb-3Mo) and Haynes 282 (Ni-20Cr-10Co-8.5Mo-2.1Ti-1.5Al). Creep testing was conducted on LPBF 718 at 600°C and 650°C and on LPBF 282 at 750°C. finding that the creep strength of the two alloys was close to that of wrought counterparts. with lower ductility at rupture. Heat treatments were tailored to the LPBF-specific microstructure to achieve grain recrystallization and form strengthening γ' precipitates for LPBF 282 and γ' and γ" precipitates for LPBF 718. In-situ data generated during printing and ex-situ X-ray computed tomography (XCT) scans were used to correlate the creep properties of LPBF 282 to the material flaw distribution. In- situ data revealed that spatter particles are the potential causes for flaws formation in LPBF 282. with significant variation between rods based on their location on the build plate. XCT scans revealed the formation of a larger number of creep flaws after testing in the specimens with a higher initial flaw density. which led to a lower ductility for the specimen.

Gas turbine blades made from nickel-based superalloys, valued for their high temperature stability and creep resistance, undergo various forms of microstructural degradation during extended service at elevated temperatures that can ultimately lead to blade failure. To extend blade and turbine rotor life, Sulzer has developed evaluation and rejuvenation processes that include microstructural assessment and stress rupture testing of specimens from service-exposed blades. While stress rupture testing presents certain limitations and challenges in evaluating material condition, Sulzer has successfully rejuvenated hundreds of gas turbine blade sets across multiple superalloy types, including GTD 111, IN 738 LC, and U 500, demonstrating the effectiveness of heat treatment rejuvenation in improving microstructure and mechanical properties of service-degraded components.

To improve the economics of critical components, such as receivers and heat exchangers, for Generation 3 (Gen 3) concentrating solar power (CSP) plants, research was conducted to understand how manufacturing impacts the high-temperature performance of various tube production routes. Gen 3 CSP components are expected to require the use of heat-resistant nickel- based alloys due to the elevated operating temperatures in designs carrying molten salt or supercritical CO 2 . INCONEL alloy 740H (alloy 740H) was investigated as an alternative to UNS N06230 (alloy 230) as it possesses superior high-temperature creep strength which can lead to overall reductions in material cost. A key challenge is understanding how autogenous seam welding with and without re-drawing can be used to manufacture thin-wall tubing for CSP receivers and heat-exchangers to further reduce costs over traditional seamless production routes. Alloy 740H welded tube was successfully fabricated and re-drawn to several relevant tube sizes. Since traditional mechanical testing samples could not be removed from the thin-wall tubing, full-sized tubes were used for tensile, fatigue, and vessel testing (internally pressurized creep- rupture) which was critical to understanding the weld performance of the manufactured product forms. The generated vessel test data exhibited a creep strength reduction when compared to wrought product with no clear trend with temperature or test duration. It was found that redrawing the welded tubes improved the creep strength to approximately 82% of the wrought material performance and elevated temperature tensile and fatigue behavior exceeded 85% of the design minimums. Detailed, post-test characterization found that nano-sized carbides formed during the laser seam-welding process remained stable after multiple solution-annealing steps, which restricted grain growth, and impacted the time-dependent performance. This paper will focus on the time-dependent behavior of the examined welded and redrawn tubes, supporting metallographic evidence, and give perspective on future considerations for using alloy 740H in CSP components.

This research compares creep crack growth behavior of two heats of creep strength enhanced ferritic (CSEF) steel, grade 91. These heats represent extremes of creep damage susceptibility, one heat exhibiting low creep ductility and the other high creep ductility. Creep crack growth tests were performed with compact tension specimens and were monitored with direct current potential drop and optical surface measurements. Load line displacement was measured throughout the duration of the tests. Specimens were sectioned, mounted, and analyzed using optical and scanning electron microscopy to assess the presence of oxidation, micro-cracking, creep damage, and void density. Tests were performed over a range of initial stress intensities on the low ductility material to investigate the impact of creep ductility. Metallurgical evidence and test data for each crack growth test was assessed to evaluate crack growth behavior linked to creep crack growth parameter (C*) and stress/creep damage distribution in the vicinity of the crack.

Inconel 718 is a nickel-based superalloy known for its excellent combination of high-temperature strength, corrosion resistance, and weldability. Additive Manufacturing (AM) has revolutionized traditional manufacturing processes by enabling the creation of complex and customized components. In this work, three prominent AM techniques: Laser-Based Powder Bed Fusion (PBF), Wire Direct Energy Deposition (DED), and Binder Jet (BJ) processes were explored. A thorough metallographic analysis and comparison of samples was conducted after short-term creep testing originating from each of the three aforementioned techniques in addition to wrought material. Detailed electron microscopy unveiled equiaxed grains in both BJ and wrought samples while PBF samples displayed elongated finer grain structures in the build direction, characteristic of PBF. The DED samples revealed a more bimodal grain distribution with a combination of smaller equiaxed grains accompanied by larger more elongated grains. When assessing the three processes, the average grain size was found to be larger in the BJ samples, while the PBF samples exhibited the most significant variation in grain and sub-grain size. Number density, size, and shape of porosity varied between all three techniques. Post-creep test observations in PBF samples revealed the occurrence of wedge cracking at the failure point, accompanied by a preference for grain boundary creep void formation while BJ samples exhibited grain boundary creep void coalescence and cracking at the failure location. In the DED samples, void formation was minimal however, it seemed to be more prevalent in areas with precipitates. In contrast, the wrought sample showed void formation at the failure site with a preference for areas with primary carbide formation. Despite BJ samples demonstrating similar or even superior rupture life compared to other AM techniques, a noteworthy reduction in rupture ductility was observed. While a coarse, uniform grain size is generally linked to enhanced creep resistance and rupture life, the combination of pre-existing voids along grain boundaries and the formation of new voids is hypothesized to accelerate rapid fracture, resulting in diminished ductility. This research shows careful consideration is needed when selecting an AM technology for high- temperature applications as creep behavior is sensitive to the large microstructural variations AM can introduce.

This paper reports on the latest in a series of projects aiming at the qualification of new and proven materials in components under a severe service environment. In the initial stages of the project (HWT I & HWT II), a test loop at Unit 6 of the GKM Power Plant in Mannheim was used to study the behavior of components for advanced ultra-supercritical (A-USC) plants made from nickel alloys at 725 °C under both static and fluctuating conditions. Due to recent changes in the operation modes of existing coal-fired power plants, the test loop was modified to continue operating the existing nickel components in the static section while applying thermal cycles in a different temperature range. HR6W pipes and valves were added to the bypass of the static section, and all components in the cyclic section were replaced with P92, P93, and HR6W components. The test loop achieved approximately 9000 hours of operation and around 800 cycles with holding times of 4 and 6 hours. After dismantling the loop, nondestructive and destructive examinations of selected components were conducted. The accompanying testing program includes results from thermal fatigue, fatigue, thermal shock, and long-term creep tests, focusing on the behavior of base materials and welds, particularly for HR6W, P92, P93, and other nickel-based alloys. Additionally, test results on dissimilar welds between martensitic steel P92 and nickel alloys A617 and HR6W are presented. Numerical assessments using standardized and numerical lifetime estimation methods complement the investigations. This paper provides insights into the test loop design and operational challenges, material behavior, and lifetime, including advanced numerical simulations and operational experiences with valves, armatures, piping, and welds.

Alloy 718 is an important class of Nb-bearing Ni-based superalloys for high-temperature applications, such as compressor disks/blades and turbine disks in gas turbine systems. The service temperature of this alloy is, however, limited below 650 °C probably due to the degradation of its strengthening phase γ"-Ni3Nb. Aiming at understanding and improving creep properties of 718-type alloys, we investigated creep behaviors of alloy 718 and alloy Ta-718 where different types of γ" phases, Ni3Nb and Ni3Ta, were precipitated, respectively. Creep tests were conducted at 700 °C under stress conditions of 400 and 500 MPa for the two alloys in aged conditions. It was found that while the minimum creep rates were comparable in the two alloys, the creep rate acceleration was lower in alloy Ta-718 than in alloy 718 under the creep conditions studied. Microstructural observations on the specimens before and after the creep tests suggested that the γ" precipitates were distinguishably finer in alloy Ta-718 than in alloy 718 throughout the creep tests. The formation of planar defects and shearing of γ" precipitates occurred frequently in the alloy 718 specimen. The observed creep deformations were discussed in terms of the critical resolved shear stress due to shearing of γ" particles by strongly paired dislocations.

This study demonstrates the Electro-Thermal Mechanical Testing (ETMT) system's capability to analyze the thermo-mechanical behavior of Inconel 718 (IN718) at a heating rate of 5 °C/s, achieving temperatures up to 950 °C. The temperature profile peaks at the sample's center and is approximately 25 °C at the extremes. Upon reaching 950 °C, the sample was aged for 30 hours before being rapidly quenched. This process froze the microstructure, preserving the phase transformations that occurred at various temperatures across the temperature parabolic gradient, which resulted in a complex gradient microstructure, providing a comprehensive map of phase transformations in IN718. The integration of thermal measurement, COMSOL modeling, scanning electron microscopy enabled a thorough characterization of the microstructural evolution in IN718, linking observed phases to the specific temperatures which provided a rapid screening of the effect of using different heating treatment routes.

This study conducted creep tests, microstructural, and hardness analyses on SA213T23-TP347H dissimilar weld joints of long-term serviced coal-fired boiler final superheater tube. The welded joint (SA213 T23-TP347H) of the superheater tube, after approximately 105,000 hours of service, was sampled for creep life assessment and maintenance planning. Creep tests were conducted at 600°C under three stress conditions: 100, 140, and 160MPa. Most cracks were observed in the heat-affected zone of T23, and compared to unused tubes, the creep life consumption rate was approximately 90%. All dissimilar weld joints used welding rods similar in chemical composition to T23, and significant hardness reduction occurred in the flame-affected zone.

In this paper, the dissimilar metal welds (DMWs) between 617B nickel-based alloy and 10%Cr martensitic heat-resistant steel filled by 617 filler metal was studied, focused on the high temperature creep rupture properties. The high temperature creep rupture properties of welded joints with different welding processes were tested, and the microstructure of welded joints before and after the creep rupture test was observed by OM and SEM. The results showed that, there were three failure modes: base metal failure, type W failure and interface failure, among which interface failure caused the most serious life reduction. The welded joints using ER NiCr-3 filler metal reduced the strain concentration at the interface, so the fracture location shifted from the interface to HAZ of 10%Cr martensitic heat-resistant steel under high temperature and low stress conditions, and creep rupture life was improved. Similarly, weld cap shifted the creep crack propagation path by changing the groove form, so as to altered the stress state of joint and prolong the creep rupture life.

Miniature specimen tests are necessary to assess the mechanical properties of new fuel cladding alloys for next-generation nuclear reactors. The small specimen allows for extensive testing programs from limited volumes of material. However, there is a lack of testing equipment to perform high-temperature mechanical tests on the miniature specimen. This work presents the development of a high-temperature creep test system for miniature specimens with in situ scanning electron microscope (SEM) testing capability for real-time characterization. Here, we discuss the challenges of the development of the system, such as gripping the samples, loading, heating, cooling mechanisms, and strain measurement. The equipment is used to investigate the creep behavior of FeCrAl alloy Kanthal APMT, and the results are compared with conventional creep test data from the same batch of this material.

Grade 91 creep strength-enhanced ferritic steel is a critical material in power generation, widely used for high-temperature, high-pressure tubing and piping applications. Its superior elevated-temperature strength derives from a distinctive microstructure of tempered martensite with uniformly dispersed secondary phases (carbides and carbo-nitrides). This microstructure, crucial for reliable service performance, is achieved through precise control of the manufacturing process, including steelmaking, hot forming, and final heat treatment. This investigation builds upon earlier research into the relationship between manufacturing parameters and short-term creep-rupture properties in T91 tubes, and a recent update that included test results exceeding 30,000 hours. This study presents a comprehensive metallurgical analysis of ruptured test specimens. The investigation focuses on correlating manufacturing parameters with not only creep strength but also material ductility and microstructural evolution during long-term exposure, providing valuable insights into the material’s behavior under extended service conditions.

This study investigates the influence of build orientation on the high-temperature mechanical properties of IN738LC manufactured via metal laser powder bed fusion (PBF-LB/M). Since the PBF-LB/M layer-wise manufacturing process significantly affects grain morphology and orientation—ranging from equiaxed to textured grains—mechanical properties typically exhibit anisotropic behavior. Samples were manufactured in three build orientations (0°, 45°, and 90°) and subjected to hot tensile and creep testing at 850°C following DIN EN ISO 6892-2 and DIN EN ISO 204 standards. While tensile properties of the 45° orientation predictably fell between those of 0° and 90° orientations, creep behavior over 100-10,000 hours revealed unexpected results: the 45° orientation demonstrated significantly shorter rupture times and faster creep rates compared to other orientations. Microstructural analysis revealed distinct creep deformation mechanisms active within different build orientations, with the accelerated creep rate in 45° specimens attributed to multiple phenomena, particularly η-phase formation and twinning. These findings provide crucial insights into the orientation-dependent creep behavior of PBF-LB/M-manufactured IN738LC components.

Olefin furnaces contain gravity cast U-bend fittings from Fe-Ni-Cr alloys that can experience premature failures due to a combination of harsh service conditions. The fittings undergo steep temperature variations during startup and shutdown, outer diameter (OD) oxidation from furnace flue gases, and inner diameter (ID) carburization from process fluids. As a result, cracking often occurs along large solidification grain boundaries from interconnected networks of carbides and secondary phases. To address these degradation concerns, Wire Arc Additive Manufacturing (WAAM) is being used to produce a functionally graded fitting that provides increased oxidation, carburization, creep, and thermal fatigue resistance. Three welding wire compositions have been designed based on thermodynamic and kinetic modeling techniques to address the appropriate corrosion resistance and mechanical properties needed in the OD, Core, and ID regions of the U- bend fitting cross-section. A Fe-35Cr-45Ni-0.7Nb solid welding wire is being used for the Core section, and metal-cored welding wires based around this composition with additions of Si or Al are being used for the OD and ID sections, respectively. This study involved weldability evaluation focused on understanding the microstructures and potential additive manufacturing printability challenges associated with graded WAAM structures using these welding wires. To achieve this, Cast Pin Tear Testing (CPTT) was performed to evaluate solidification cracking susceptibility of the welding wires. Additionally, Scheil calculations were performed in Thermo-Calc software to predict solidification microstructures. To validate the results, SEM characterization was conducted on cast buttons of each welding wire to identify phases in the respective microstructures. These unique data will help inform WAAM design parameters needed to produce a Functionally Graded Material (FGM) that improves the lifetime of Fe-Ni-Cr U-bend fittings in olefin furnaces.?

Ni-base superalloys used for hot section hardware of gas turbine systems experience thermomechanical fatigue (TMF), creep, and environmental degradation. The blades and vanes of industrial gas turbines (IGTs) are made from superalloys that are either directionally-solidified (DS) or cast as single crystals (SX). Consequently, designing and evaluating these alloys is complex since life depends on the crystallographic orientation in addition to the complexities related to the thermomechanical cycling and the extent of hold times at elevated temperature. Comparisons between the more complex TMF tests and simpler isothermal low cycle fatigue (LCF) tests with hold times as cyclic test methods for qualifying alternative repair, rejuvenation, and heat-treatment procedures are discussed. Using the extensive set of DS and SX data gathered from the open literature, a probabilistic physics-guided neural network is developed and trained to estimate life considering the influence of crystallographic orientation, temperature, and several other cycling and loading parameters.

There is an increased interest in miniature testing to determine material properties. The small punch test is one miniaturized test method that has received much interest and is now being applied to support the design and life assessment of components. This paper presents the results of a test program for a small punch creep test at 650°C of 316L stainless steel produced from additive manufacturing. A major finding is that the deflection rate curve versus time may have multiple minima as opposed to forged 316L with only one minimum. This is believed to be due to microcracking and has direct consequences on the determination of the creep properties that that are based on a single minimum value in the CEN Small Punch Standard. In the paper, aged and nonaged materials are compared, and small punch creep results are also compared with standard uniaxial creep tests. The multiple minima feature means that the approach to determine equivalent stress and strain rate from the minimum deflection rate needs to be modified. Some approaches for this are discussed in the paper. Under the assumption that the multiple minima represent cracking, it opens up opportunities to quantify reduced creep ductility by the small punch test.

Hydrogen as a clean fuel is increasingly being used to propel gas turbines and to power combustion engines. Metallic materials including Ni-based alloys are commonly used in conventional gas turbines and combustion engines. However, hydrogen may cause embrittlement in these materials, depending on their chemical composition. In this work, the hydrogen embrittlement behavior of Ni-based alloys containing up to 50 wt.% Fe has been investigated using slow strain rate tensile testing, under cathodic hydrogen charging at room temperature. It was found that the larger the Ni equivalent concentration in an alloy, the more severe the hydrogen embrittlement. It was also found that solid solution alloys have less severe hydrogen embrittlement than precipitation alloys of the same Ni equivalent concentration. In solid solution alloys, hydrogen embrittlement led to cleavage type fracture, which is in line with literature where hydrogen enhanced planar deformation. In precipitation alloys, hydrogen embrittlement resulted in a typical intergranular fracture mode.