The mechanical behavior of a cast form of an advanced austenitic stainless steel, CF8C-Plus, is compared with that of its wrought equivalent in terms of both tensile and creep-rupture properties and estimated allowable stress values for pressurized service at temperatures up to about 850°C. A traditional Larson-Miller parametric model is used to analyze the creep-rupture data and to predict long-term lifetimes for comparison of the two alloy types. The cast CF8C-Plus exhibited lower yield and tensile strengths, but higher creep strength compared to its wrought counterpart. Two welding methods, shielded-metal-arc welding (SMAW) and gas-metal-arc welding, met the weld qualification acceptance criteria in ASME BPVC Section IX for the cast CF8C-Plus. However, for the wrought CF8C-Plus, while SMAW and gas-tungsten-arc welding passed the tensile acceptance criteria, they failed the side bend tests due to lack of fusion or weld metal discontinuities.

As many nuclear power plants are in the license renewal operating period and some are entering subsequent license renewal, there is increased probability that repairs will be needed on components that have been exposed to significant neutron fluence. The neutron-driven transmutation of nickel and tramp boron in austenitic materials commonly used in reactor internals can lead to the generation of trapped helium and the associated risk of helium-induced cracking (HeIC) during weld repairs. In the weld heat affected zone, where temperatures are insufficient to allow the helium to diffuse out of the material, the helium can remain trapped. Upon cooling, the residual stresses, combined with weakened grain boundaries due to helium coalescence, can lead to cracking. The current ASME limit for helium content for Code repairs is 0.1 appm. Prior work has demonstrated a strong inverse correlation between helium content and permissible weld heat input for avoidance of HelC. The helium concentration in the material to be repaired is thus a critical input to the development of weld repair processes to be applied to these materials. The reliable measurement of helium in irradiated materials at concentrations relevant for the evaluation of HeIC risk is a specialized process. It is important to demonstrate that the capability is available and can be practically leveraged to support emergent repairs. This paper presents on the execution and results of a multi-laboratory test program aimed at demonstrating the industry capability of acquiring accurate, repeatable, and timely measurements of relatively low concentrations of helium (< ~20 appm) within austenitic materials commonly used in reactor internals. Participating laboratories were supplied with equivalent specimens extracted from boron-doped coupons that were irradiated to drive the boron-to-helium transmutation reaction. The results and lessons learned from the program are expected to support the development of industry guidance for the acquisition of similar measurements supporting nuclear component repairs.

NAC International Inc. (NAC) is providing transportable storage canisters (TSCs) to Central Plateau Cleanup Company CPCCo) for long term dry storage of capsulized radioactive waste at the Hanford Site in Richland, WA. The TSC consists of 316/316L stainless-steel components welded to form a cylindrical canister that acts as a confinement boundary for the payload. The heat affected zones of the welded areas are most susceptible to Chloride Induced Stress Corrosion Cracking (CISCC), that may limit the life of the TSC. To mitigate CISCC during the anticipated 300-year storage period, an overcoating is applied to the heat affected zones of all external TSC fabrication welds, referred to as Cold Spray. This paper will discuss the purpose, development, and application of Cold Spray to the CPCCo TSCs. Cold Spray is a process whereby metal powder particles are deposited upon a substrate by means of ballistic impingement via a high-velocity stream of gas, resulting in a uniform deposition with minimal porosity and high bond strength. Temperatures are below the melting thresholds of many engineering materials enabling a large variety of application uses. NAC developed a process for Cold Spray application onto the 316/316L stainless-steel TSCs to serve as a CISCC protective/mitigative coating for its canister products. Testing during development arrived at nickel as the deposited coating material and nitrogen as the gas vehicle, along with a set of various application parameters. The qualified process was implemented onto the CPCCo TSCs. Prior to application, the equipment and process are validated via coupons that are sprayed and then tested to meet requirements for adhesion strength (ASTM C633) and porosity (ASTM E2109). After successful coupon testing, Cold Spray is performed on the external TSC fabrication welds, to include heat affected zones. Acceptance testing of the resulting deposition is performed via visual inspection.

Nuclear reactor inspections occasionally identify degraded materials in irradiated reactor components. Although mechanical repair options are possible, these repair solutions may be cost prohibitive or impractical to implement due to access restraints and/or the severity of the degradation. Welding repair of reactor components may input excessive heat into these irradiated materials resulting in diffusion of trace amounts of helium within the grain boundaries of the weld heat-affected zone (HAZ). Intergranular HAZ cracking can then result from the combination of this helium diffusion and high localized tensile stresses generated during weld cooling. It is therefore critical to characterize these zones and understand limitations for welding highly irradiated components to prevent helium-induced cracking. To accomplish this, typical reactor structural materials including Types 304L and 316L stainless steels and nickel-based Alloy 600/182 materials irradiated within the High Flux Isotope Reactor facility at Oak Ridge National Laboratory were used in this study for welding and evaluation. A phased array ultrasonic inspection system has been developed to characterize cracking in the weld samples. It provides remote controlled scanning and minimizes handling the samples, minimizing operator dose. The samples are inspected from the side opposite of the welds. The material and weld grain noise were evaluated at 10 MHz and found to be conducive to detecting cracking in the material and welds. Inspection of the samples comprises a 10 MHz phased array probe sweeping a focused longitudinal wave from -60° to 60° while the probe is raster scanned over the sample in small increments. The collected data is analyzed using UltraVision 3. Several of the irradiated samples were inspected prior to welding. Some of the samples had what appear to be small lamination defects in them. One irradiated welded sample has been tested to date with no cracking detected, which has been confirmed by destructive examination.

This study conducted creep tests, microstructural, and hardness analyses on SA213T23-TP347H dissimilar weld joints of long-term serviced coal-fired boiler final superheater tube. The welded joint (SA213 T23-TP347H) of the superheater tube, after approximately 105,000 hours of service, was sampled for creep life assessment and maintenance planning. Creep tests were conducted at 600°C under three stress conditions: 100, 140, and 160MPa. Most cracks were observed in the heat-affected zone of T23, and compared to unused tubes, the creep life consumption rate was approximately 90%. All dissimilar weld joints used welding rods similar in chemical composition to T23, and significant hardness reduction occurred in the flame-affected zone.

In this paper, the dissimilar metal welds (DMWs) between 617B nickel-based alloy and 10%Cr martensitic heat-resistant steel filled by 617 filler metal was studied, focused on the high temperature creep rupture properties. The high temperature creep rupture properties of welded joints with different welding processes were tested, and the microstructure of welded joints before and after the creep rupture test was observed by OM and SEM. The results showed that, there were three failure modes: base metal failure, type W failure and interface failure, among which interface failure caused the most serious life reduction. The welded joints using ER NiCr-3 filler metal reduced the strain concentration at the interface, so the fracture location shifted from the interface to HAZ of 10%Cr martensitic heat-resistant steel under high temperature and low stress conditions, and creep rupture life was improved. Similarly, weld cap shifted the creep crack propagation path by changing the groove form, so as to altered the stress state of joint and prolong the creep rupture life.

High gamma prime Ni-based superalloys comprising ≥3.5 % Al are difficult to weld due to high propensity of these materials to weld solidification, heat affected zone liquation, and stress-strain cracking. In this study the root cause analysis of cracking and overview on the developed weldable Ni-based superalloys for repair of turbine engine components manufactured from equiaxed (EA), directionally solidified (DS), and single crystal (SX) materials as well as for 3D AM is provided. It is shown that the problem with the solidification and HAZ liquation cracking of turbine engine components manufactured from EA and DS superalloys was successfully resolved by modification of welding materials with boron and silicon to provide a sufficient amount of eutectic at terminal solidification to promote self-healing of liquation cracks along the weld - base material interface. For crack repair of turbine engine components and 3D AM ductile LW4280, LW7901 and LCT materials were developed. It is shown that LW7901 and LCT welding materials comprising 30 - 32 wt.% Co produced sound welds by GTAW-MA on various SX and DS materials. Welds demonstrated high ductility, desirable combination of strength and oxidation properties for tip repair of turbine blades. Examples of tip repair of turbine blades are provided.

The incore instrumentation system of a pressurized water reactor (PWR) facilitates neutron flux mapping and temperature measurements at specific core locations. A guide conduit, extending from the seal table to the lower reactor pressure vessel head, guides and protects each incore guide thimble between the table and the lower reactor vessel head. Each flux thimble houses a detector and drive cable. Once filled with reactor coolant, the conduit becomes an extension of the reactor coolant pressure boundary. This paper reports the examination results of cracking detected in a TP304 stainless steel guide conduit adjacent to a fillet weld at the upper surface of a TP304 seal table. The cracking resulted in reactor coolant leakage that was detected by the presence of boric acid deposits on the exterior of the conduit and table. Failure analysis including dimensional measurements, chemical analysis, stereomicroscopy, metallography, and scanning electron microscopy showed that extensive cracking of the conduit and seal table material occurred due to stress corrosion cracking (SCC). Assessment showed that chlorine-containing deposits were present on the exterior of the conduit and on the surfaces of the seal table and were due to the design and operation of HVAC systems at the coastal plant. Stainless steels are susceptible to SCC in environments with elevated temperatures, chloride contents, and increased tensile stress – particularly in non-post weld heat treated (PWHT) weld regions and the heat affected zone (HAZ). This was the apparent primary cause of the failure. However, chloride-induced SCC of such materials typically results in transgranular crack propagation, whereas the observed cracks were indicative of intergranular stress corrosion cracking (IGSCC). Microstructural analysis showed that the observed cracks initiated in sensitized areas of material adjacent to the weld. Sensitization of the material caused chromium depletion from adjacent areas and increased susceptibility of the depleted areas to IGSCC. In this case, the most probable source of sensitization was related to welding and the long-term growth of grain boundary carbides nucleated during welding. This was considered a contributing cause to the failure.

This study investigates a novel approach to addressing the persistent Type IV cracking issue in Grade 91 steel weldments, which has remained problematic despite decades of service history and various mitigation attempts through chemical composition and procedural modifications. Rather than further attempting to prevent heat-affected zone (HAZ) softening, we propose eliminating the vulnerable base metal entirely by replacing critical sections with additively manufactured (AM) weld metal deposits using ASME SFA “B91” consumables. The approach employs weld metal designed for stress-relieved conditions rather than traditional normalizing and tempering treatments. Our findings demonstrate that the reheat cycles during AM buildup do not produce the substantial softening characteristic of Type IV zones, thereby reducing the risk of premature creep failure. The study presents comprehensive properties of the AM-built weld metal after post-weld heat treatment (PWHT), examines factors influencing deposit quality and performance, and explores the practical benefits for procurement and field construction, supported by in-service data and application cases.

Diffusion bonded compact heat exchangers have exceptionally high heat transfer efficiency and might significantly improve the performance and reduce the cost of supercritical carbon-dioxide Brayton cycle power plants using high temperature heat sources, like high temperature nuclear reactors and concentrating solar power plants. While these heat exchangers have an excellent service history for lower temperature applications, considerable uncertainty remains on the performance of diffusion bonded material operating in the creep regime. This paper describes a microstructural modeling framework to explore the plausible mechanisms that may explain the reduced creep ductility and strength of diffusion bonded material, compared to wrought material. The crystal plasticity finite element method (CPFEM) is used to study factors affecting bond strength in polycrystals mimicking diffusion bonded microstructures. Additionally, the phase field method is also employed to simulate the grain growth and recrystallization at the bond line to model the bonding process and CPFEM is used to predict the resulting material performance to connect processing parameters to the expected creep life and ductility of the material, and to study potential means to improve the structural reliability of the material and the resulting components by optimizing the material processing parameters.

In this study, the creep strength of welded joints of Grade 91 Type 1 and Type 2 steels was evaluated. It was determined that impurity elements in the Type 1 steel reduced its creep strength. This reduction was attributed to an increase in the amount of residual carbides in the fine-grain heat-affected zone during welding.

Tenaris' High Oxidation Resistance (THOR) 115, or T115, is a creep strength-enhanced ferritic (CSEF) steel introduced in the past decade. It is widely used in constructing high-efficiency power plants and heat recovery steam generators (HRSGs) due to its superior steam oxidation resistance and long-term microstructural stability, making it a viable alternative to stainless steels at elevated steam temperatures. The creep damage tolerance of T115 has been recently validated under ASME BPVC CC 3048 guidelines, which address safety concerns related to creep damage in boiler components. Testing confirmed T115's consistent creep damage-tolerant behavior, with cross-weld creep behavior reassessed through extensive metallographic examination of specimens from a 1.5-inch thick pipe girth weld, providing insights into creep damage distribution and hardness, and its relative performance compared to Grade 91 CSEF steel.

In dissimilar welds between martensitic stainless steel F6NM and nitrogen-strengthened austenitic stainless steel FXM-19, type 209 austenitic welding consumables are used to align with the mechanical properties and chemical composition of FXM-19, with F6NM welds requiring post-weld heat treatment (PWHT) to restore ductility and toughness, raising concerns about sigma embrittlement in ER209 butter welds. This study investigated the mechanical properties and microstructure of F6NM+FXM-19 dissimilar welds, finding no detrimental sigma phase formation in the butter (PWHT) and groove weld metal (as welded) across various welding processes, indicating no sigma phase transformation due to PWHT. Submerged arc welding (SAW) and gas tungsten arc welding (GTAW) demonstrated good mechanical properties, while Gas Metal Arc Welding with 100% Ar gas shield (GMAW 100% Ar) could not be properly evaluated due to weld defects. SAW and GTAW were deemed suitable for this dissimilar weld joint, with several welding processes providing acceptable results using ER209 filler material for fabricating pressure vessels requiring F6NM to XM-19 joints.

Coke drums experience failures in through-wall cracking throughout their operating life, resulting from low cycle fatigue. Coke drums are typically fabricated from Chrome Moly (CrMo) steels. This study was performed on P4 (1.25Cr-0.5Mo) base material using ER70S-B2L and Alloy 625 (ERNiCrMo-3) filler materials. Specimens were welded with the temper-bead/controlled deposition welding technique. The weld processes used were HP-GTAW, GMAW and SMAW. The fatigue performance, HAZ hardness and toughness of the weld samples was evaluated. The HP-GTAW welds exhibited an order of magnitude improvement in fatigue performance when compared to the other weld processes using ER70S-B2L filler material. The HP-GTAW welds also exhibited improved HAZ hardness and toughness when compared to the other weld processes. This presentation will introduce the HP-GTAW process, its features, and benefits and where it is applied in Coke drum repair welding. Comparative test results of the different weld processes for fatigue performance, HAZ tempering, and toughness will also be presented.

According to ASME Case N-888-3, Similar and Dissimilar Metal Welding Using Ambient Temperature SMAW or Machine GTAW Temper Bead Technique, a 48 hr waiting period before conducting the final nondestructive examination (NDE) is required when ferritic filler weld metal is used. The purpose of the 48 hr hold is to confirm the absence of hydrogen-induced cracking in the temper bead heat-affected zone. In previous research, the effect of post-weld heat treatment (PWHT) and temper bead welding (TBW) on the hydrogen-induced cracking (HIC) susceptibility in the coarse-grained heat-affected zone (CGHAZ) in welds of SA-508, P-No. 3 Group 3, pressure vessel steel was investigated using the Delayed Hydrogen Cracking Test (DHCT). In that previous study, the Gleeble thermomechanical simulator was used to generate six CGHAZ microstructural conditions: as-welded (AW), PWHT, and AW with single a TBW reheat at 675, 700, 725, and 735°C. Hydrogen was introduced to the specimen through cathodic charging under in situ constant tensile stress. The HIC susceptibility for these microstructures was ranked by the DHCT at a diffusible hydrogen level significantly exceeding typical GTAW and SMAW processes. The work described in this paper investigates the susceptibility to HIC of these same CGHAZ microstructures with DHCT at variable current densities, further ranking each condition. Test results were analyzed by fracture surface examination of failed tests, and cross-section microstructural analysis under a scanning electron microscope (SEM). Future steps include evaluating critical hydrogen content levels using gas chromatography for each condition. The results from this study will be used to consider potential elimination of the NDE hold time requirement in Case N-888-3 when ferritic weld metal is used.

This study evaluates various nondestructive testing methods for detecting creep damage and assessing residual life in Grade 91 steel welds. Three primary detection techniques were investigated: phased array ultrasonic testing (PAUT), eddy current testing with high-temperature superconductor direct current and superconducting quantum interference device (ECT•HTS-dc-SQUID), and replica observation. PAUT detected creep damage between 60-80% of creep life, while ECT•HTS-dc-SQUID showed detection capability between 80-90% of creep life. Replica observation revealed creep voids only in the final stages before rupture. Additionally, three strain measurement methods were evaluated: capacitive strain sensors (providing continuous monitoring during creep exposure), laser displacement meters (used during test interruptions), and SPICA strain measurement. Both capacitive sensors and laser meters produced results comparable to conventional extensometer measurements. The SPICA method proved particularly effective in measuring heat-affected zone (HAZ) strain after creep exposure, revealing higher strain values in the HAZ compared to base and weld metal, with a consistent increase during creep exposure.

This study addresses the welding challenges encountered when joining Haynes 282, a heat-resistant superalloy, to 3.5NiCrMoV high-strength low alloy steel (HSLA) for advanced power plant applications, particularly in thick-section components like rotors. The project demonstrated successful thick-section dissimilar metal welding up to 76 mm (3 in.) using two techniques: keyhole tungsten inert gas welding and conventional gas tungsten arc welding with Haynes 282 filler metal. Various groove weld geometries were evaluated, supported by computational weld modeling to predict and minimize weld distortion. The results validate these welding approaches for critical power plant components requiring both high-temperature performance and cost-effectiveness.

This paper presents three recent example cases of cracking in Grade 91 steel welds in longer-term service in high temperature steam piping systems: two girth butt welds and one trunnion attachment weld. All the cases were in larger diameter hot reheat piping, with the service exposure of the welds ranging from approximately 85,000 to 150,000 hours. Cracking in all cases occurred by creep damage (cavitation and microcracking) in the partially transformed heat-affected zone (PTZ, aka Type IV zone) in the base metal adjacent to the welds. The location and morphology of the cracking are presented for each case along with operating conditions and potential contributors to the cracking, such as system loading, base metal chemical composition, and base metal microstructure.

Creep strength enhanced ferritic (CSEF) steels have shown the potential for creep failure in the weld metal, heat affected zone (HAZ) or fusion line. Details for this behavior have been frequently linked to metallurgical risk factors present in each of these locations which may drive the evolution of damage and subsequent failure. This work is focused on three weld samples fabricated from a commercially sourced Grade 92 steel pipe section. These weld samples were extracted from the same welded section but were reported to exhibit failure in different time frames and failure locations (i.e., HAZ of parent, fusion-line, and weld metal). The only variables that contribute to this observed behavior are the post weld heat treatment (PWHT) cycle and the applied stress (all tests performed at 650 °C). In this work detailed microstructural analysis was undertaken to precisely define the locations of creep damage accumulation and relate them to microstructural features. As part of this an automated inclusion mapping process was developed to quantify the characteristics of the BN particles and other inclusions in the parent material of the samples. It was found that BN particles were only found in the sample that had been subjected to the subcritical PWHT, not those that had received a re-normalizing heat treatment. Such micron sized inclusions are a known potential nucleation site for creep cavities, and this is consistent with the observed failure location in the HAZ of the parent in the sample where these were present. In the absence of BN inclusions, the next most susceptible region to creep cavitation is the weld metal. This has an intrinsically high density of sub-micron sized spherical weld inclusions and this is where most of the creep damage was located, in all the renormalized samples.

The localized creep failure in the heat-affected zone (HAZ) of Grade 91 steel weldments has been identified as one of the most important factors causing significantly shortened service lifetime and structural integrity issues of welded components in advanced fossil and nuclear power plants. To conduct a reliable creep lifetime assessment, a new engineering assessment approach has been developed by incorporating the experimentally determined local properties of the heterogeneous HAZ. By creep testing a purposely simulated HAZ specimen with in situ digital image correlation (DIC) technique, the highly gradient creep properties across the HAZ of Grade 91 steel was quantitatively measured. A physical creep cavitation constitutive model was proposed to investigate the local creep deformation and damage accumulation within the heterogeneous HAZ, which takes into account the nucleation of creep cavities and their growth by both grain boundary diffusion and creep deformation. The relationship among the local material property, creep strain accumulation, and evolution characteristic of creep cavities was established. The approach was then utilized to investigate the creep response and subsequent life for an ex-service 9% Cr steel weldment by incorporating the effects of pre-existing damages which developed and accumulated during long-term services. The predicted results exhibited quantitative agreement with the DIC measurement in terms of both nominal/local creep deformation as well as the subsequent life under the test conditions at 650 and 80 MPa.