A Japanese national project has been undertaken since Aug. 2008 with the objective of developing an advanced ultra-supercritical power plant (A-USC) with a steam temperature of 700°C. Fe-Ni and Ni-based alloys, namely HR6W, HR35, Alloy617, Alloy740, Alloy263 and Alloy141, were taken as candidate materials for piping and superheater/reheater tubes in an A-USC boiler. Weldments of these alloys were manufactured by GTAW, after which long term creep rupture tests were conducted at 700°C, 750°C and 800°C. Weldments of HR6W, HR35 and Alloy617 showed similar creep strength as compared with these base metals. Weldments of Alloy740 tended to fail in the HAZ, and it is considered that voids and cracks preferentially formed in the small precipitation zone along the grain boundary in the HAZ. The creep strength of Alloy263 in weldments exhibited the highest level among all the alloys, although HAZ failure occurred in the low stress test condition. A weld strength reduction factor will be needed to avoid HAZ failure in Alloy740 and Alloy263. Also, to prevent premature failure in weld metal, optimization of the chemical composition of weld filler materials will be required.

Boron and nitride additions are emerging as a promising design concept for stabilizing the microstructure of creep-resistant martensitic high-chromium steels. This approach, known as MarBN steel (martensitic steel strengthened by boron and nitrogen), combines the benefits of solid solution strengthening from boron with precipitation strengthening from nitrides. However, initial welding trials revealed challenges in achieving a uniform fine-grained region in the heat-affected zone (HAZ), which is crucial for mitigating Type IV cracking and ensuring creep strength. Despite these initial hurdles, preliminary creep test results for welded joints have been encouraging. This study presents an improved MarBN steel formulation and its investigation through uniaxial creep tests. Base material and welded joints were subjected to creep tests at 650°C for up to 25,000 hours under varying stress levels. The analysis focused not only on the creep strength of both the base material and welded joints but also on the evolution of damage. Advanced techniques like synchrotron micro-tomography and electron backscatter diffraction were employed to understand the underlying creep damage mechanisms. By combining long-term creep testing data with 3D damage investigation using synchrotron micro-tomography, this work offers a novel perspective on the fundamental failure mechanisms occurring at elevated temperatures within the HAZ of welded joints in these advanced steels.

Increasing demand on efficiency and power output of steam generators leads to new designs of welded rotors. The reason for rotor welding is the large size of rotors, which are difficult to produce in a single piece. Secondly, as there are varying operation conditions along the rotor length. In a heterogeneous rotor, several materials appropriate for local service conditions can be used. At the rotor service temperatures, creep properties are crucial for successful design. The weakest point of every welded component is the heat affected zone. Therefore, the creep properties of a heterogeneous weld are subject of the investigation herein the current study, a heterogeneous weld of COST F and COST FB2 materials is investigated. The welding was performed by multi pass technique with overlaying welding beads that applied several heating cycles to heat affected zone. Metallographic investigation of the weld was performed and the weakest microstructure spots were detected. With the use of FEM simulation, appropriate heating/cooling cycles were obtained for the detected weak points. The temperature cycles obtained were subsequently applied to both base materials under laboratory conditions by induction heating. Creep properties of these materials were investigated. The influence of the initial base material’s grain size was also considered in the investigation. Two heating/cooling schedules were applied to both base materials with two grain sizes. Altogether, 8 different microstructures were examined in short term creep tests and the results were summarized.

Flux cored wires are worldwide used in power generation industry due to their technical and economic advantages. For welding P91 and P92 flux cored wires with a rutile slag system are available for several years. Results of long-term investigations up to 30.000 h show that specimens of all weld metal meet the requirements of the base material. Following the recent demand of reduced Mn+Ni content the chemical composition of all weld metal has been modified. For P91 a matching flux cored wire with Mn+Ni<1wt% and for P92 with Mn+Ni<1.2wt% is now available. In this paper the mechanical properties of all weld metal and welded joints are being presented. Latest developments in cast materials have shown that the so-called CB2 (GX13CrMoCoVNbNB 10-1-1) enables steam temperatures up to 620°C (1148°F). Therefore a matching flux cored wire with low Ni-content has been developed. Results of welding procedure qualification and first experience of manufacturing industrial components show the successful implementation of this new material grade and welding consumable.

The creep rupture properties of welded joints of advanced 9%Cr-Mo-Co-B steel used for 620°C USC steam turbine have been studied. The welded joints were prepared by means of shielded metal arc welding (SMAW). A lot of creep tests have been conducted and the results indicate that fracture usually occurs in the intercritical heat affected zone (ICHAZ) of the welded joint and is typical of Type IV cracking. The microstructure of the HAZ has been investigated by using optical microscopy, SEM and TEM. The degradation mechanism of welded joint of the 9%Cr-Mo-Co-B steel has been explored by analysing the phases of precipitates. Creep voids were observed in the vicinity of the coarse Laves phase particles, resulting in the degradation of the creep rupture properties.

In order to improve thermal efficiency of fossil-fired power plants through increasing steam temperature and pressure high strength martensitic 9-12%Cr steels have extensively been used, and some power plants have experienced creep failure in high temperature welds after several years operations. The creep failure and degradation in welds of longitudinally seam-welded Cr- Mo steel pipes and Cr-Mo steel tubes of dissimilar metal welded joint after long-term service are also well known. The creep degradation in welds initiates as creep cavity formation under the multi-axial stress conditions. For the safety use of high temperature welds in power plant components, the complete understanding of the creep degradation and establishment of creep life assessment for the welds is essential. In this paper creep degradation and initiation mechanism in welds of Cr-Mo steels and high strength martensitic 9-12%Cr steels are reviewed and compared. And also since the non-destructive creep life assessment techniques for the Type IV creep degradation and failure in high strength martensitic 9-12%Cr steel welds are not yet practically established and applied, a candidate way based on the hardness creep life model developed by the authors would be demonstrated as well as the investigation results on the creep cavity formation behavior in the welds. Additionally from the aspect of safety issues on welds design an experimental approach to consider the weld joint influence factors (WJIF) would also be presented based on the creep rupture data of the large size cross-weld specimens and component welds.

Qualifying welding procedures for repair of components in high temperature service requires careful consideration of factors including identification of the materials involved, existing mechanical properties and service operating parameters such as temperature, pressure and environment. Selection of weld metals to match, under match or overmatch base material as well as direct and indirect consequences on the heat-affected zone also require evaluation. Application of post weld heat treatment and ramifications where dissimilar base materials are involved are discussed plus the necessity of conducting tests at the operating temperatures and conditions where information is not available from the literature. Each of these factors is discussed and examples provided.

This study investigates the impact of adding small amounts of rare earth (RE) elements on the properties and microstructures of SA335P91 steel welds. The RE elements were incorporated into the weld metal using a coating process. The researchers then proposed an optimal RE formula aimed at achieving improved properties and microstructures. To evaluate the effectiveness of this approach, various tests were conducted on both welds with and without RE additions. These tests included tensile testing (both at room and high temperatures), impact testing, metallographic analysis to examine the microstructure, determination of phase transformation points, scanning electron microscopy, and X-ray diffraction. The results revealed that the addition of RE elements has the potential to enhance the properties and modify the microstructure of SA335P91 welds.

Dynamic development of steels used in power engineering industry for the production of boilers characterised by supercritical parameters poses new welding challenges. The introduction of new combinations of alloying agents aimed at obtaining the best possible mechanical properties, including creep resistance, affects the weldability of new steels. Each of the latter have to undergo many tests, particularly as regards bending and welding, in order to enable the development of technologies ensuring failure-free production and assembly of boiler systems. Martensitic steels containing 9% Cr, used in the manufacturing of steam superheaters, are characterised by good creep resistance and, at the same time, low oxidation resistance at a temperature in excess of 600°C. In turn, steels with a 12% Cr content are characterised by significantly higher oxidation resistance, but accompanied by lower strength at higher temperatures, which translates to their limited application in the production of boilers operating at the highest parameters. The niche between the aforesaid steels is perfectly filled by austenitic steels, the creep resistance and oxidation resistance of which are unquestionable. This article presents experience gained while welding dissimilar joints of advanced steels TEMPALOY AA-1 and T92, with the use of EPRI P87, Inconel 82 and Inconel 617 filler metals. The tests involving the said steel grades belong to the very few carried out in the world.

In recent years continuous and extensive research and development activities have been being done worldwide on 700°C A-USC (Advanced Ultra Super Critical) power plants to achieve higher efficiency and reduce the CO 2 emission. Increasing steam temperature and pressure of such A-USC boilers under consideration require the adoption of Ni based alloys. In the Japanese national project launched in 2008, Ni based alloy HR6W (45Ni-23Cr-7W-Ti, ASME Code Case 2684) is one of the candidate materials for boiler tube and pipe as well as Alloy617, Alloy263 and Alloy740H. The most important issues in A-USC boiler fabrication are the establishment of proper welding process for thick wall components of these alloys and verification of the long term reliability of their weldments. In our previous study, the weldability of HR6W was investigated and the welding process for Ni based thick wall pipe was established with the narrow gap HST (Hot wire Switching TIG) welding procedure originally developed by Babcock-Hitachi K.K. In this paper, creep rupture strengths of HR6W weldment were verified by the long term test up to 60,000 hours for tube and 40,000 hours for pipe. In Japanese national project, narrow gap HST welding process was also applied to the welding test for the other Ni based candidate pipe materials. Furthermore, as the practical A-USC boiler manufacturing trials, header mockup test was conducted and qualified for HR6W.

This paper summarizes recent efforts to improve creep performance in Grade 91 (Mod. 9Cr-1Mo, ASTM A387) steel weldments via non-standard heat treatments prior to welding. Such heat treatments offer a potential solution for minimizing Type IV failures in creep strength enhanced ferritic (CSEF) steels. A lower temperature tempering (LTT, 650°C) of the 9Cr steels prior to gas tungsten arc welding (GTAW) resulted in improved creep-rupture life at 650°C compared to the samples tempered at a standard condition (HTT, 760°C) before welding. From detailed characterization of precipitation kinetics in the heat affected zone, it was hypothesized that M 23 C 6 carbides in the fine-grain heat-affected zone (FGHAZ) in the LTT sample were fully dissolved, resulting in re-precipitation of strengthening carbides during post weld heat treatment (PWHT). This was not the case in the HTT sample since M 23 C 6 in the FGHAZ was only partially dissolved prior to welding, which caused coarsening of existing M 23 C 6 after PWHT and premature creep failure in the FGHAZ. However, it was also found that the LTT raised the ductile-brittle transition temperature above room temperature (RT). Two different thermo-mechanical treatments (TMTs); two-step tempering and aus-forging/aus-aging, of the modified 9Cr-1Mo steels were attempted, in order to control the balance between creep properties and RT ductility, through control of precipitation kinetics of the M 23 C 6 carbides and/or MX carbo-nitrides. The hardness map of the TMT samples after GTAW and PWHT were evaluated.

The use of high-nickel superalloys has greatly increased among many industries. This is especially the case for advanced coal-fired boilers, where the latest high temperature designs will require materials capable of withstanding much higher operating temperatures and pressures than current designs. Inconel alloy 740H (UNS N07740) is a new nickel- based alloy that serves as a candidate for steam header pipe and super-heater tubing in coal-fired boilers. Alloy 740H has been shown to be capable of withstanding the extreme operating conditions of an advanced ultra-super-critical (AUSC) boiler, which is the latest boiler design, currently under development. As with all high nickel alloys, welding of alloy 740H can be very challenging, even to an experienced welder. Weldability challenges are compounded when considering that the alloy may be used in steam headers, where critical, thick-section and stub-to-header weld joints are present. This paper is intended to describe the proper procedures developed over years of study that will allow for ASME code quality welds in alloy 740H with matching composition filler metals.

Finite element (FE) modeling has been applied to a stress relaxation cracking (SRC) test in order to evaluate the effects of changing sample geometry and material type. This SRC test uses compressive pre-straining to create a tensile residual stress in modified compact-tension specimens and has been used to test 316H stainless steel. The FE model is first used to verify that sample integrity will not be compromised by modifying the geometry. The FE model is then applied to candidate Advanced Ultra Supercritical nickel-base alloys 617, 740H, and 800. It is determined that this stress relaxation test will be appropriate for these alloys.

Welding processes and fabrication techniques have been studied in the development of Advanced USC boilers. Advanced 9Cr steels, Fe-Ni alloy (HR6W) and Nickel base alloys (HR35, Alloy 617, Alloy 263, Alloy 740 and Alloy 740H) have been selected as candidate materials for the boiler. The weld joints of these alloys were prepared from plates, small diameter tubes and large pipes, and welding procedure tests were performed. In this study, TIG and SMAW were applied. Both welding process produced good weld joints, and they showed good results in bending tests, tensile tests and the Charpy impact test. To select the annealing conditions for stress relief, stress relaxation tests and hardness tests were conducted on the weld joints after various heat treatments. The microstructure was also evaluated by SEM and TEM. Creep rupture tests are being performed for the weld joints with and without heat treatment. The maximum creep rupture tests are expected to take over 100,000 hours. In the study of fabrication techniques, hot bending tests by high frequency induction heating for large pipes and cold/hot bending tests for small diameter tubes were established. After the bending tests, mechanical property tests such as tensile tests, impact tests and creep rupture tests were conducted. The effect of pre-strain on creep strength was studied to take the creep test results after bending into consideration. The creep rupture test will be continued for specimens from weld joints and bending pipes to show their long term reliability.

Material properties and damage mechanisms exhibit significant variation across weldments. Micro tensile (MT) testing of specimens machined from specific narrow weldment zones is one method to characterize local property variation. Although limited, the literature data on micro-tensile specimen testing reports on low-temperature behavior. However, cross-weld local material data at high service temperatures have not been reported yet. In the present study, MT tests are conducted across similar P22 and P91 steel welds at 550°C and 600°C, respectively. To study deformation mechanisms and the role of surface condition on properties, specimens with different surface conditions (machined, polished, and electropolished) are tested. Two different loading rates of 0.2 mm/min and 0.5 mm/min are used to study the effect of loading rate on deformation and mechanical properties. Variations in weldment material properties are presented as a function of specimen surface conditions and loading speeds. Deformation behavior is studied on the side surfaces of tested micro-tensile specimens using SEM. Deformation is correlated to the microstructural constituent observed on side surfaces.

Investigations on welded joints made from a modified parent material and welding consumables are described. Tubes and pipes with typical dimensions have been welded using different welding processes and consumables (GTAW, SAW, SMAW, modified filler metals). The influence of melting loss and chemical composition of the consumables on the weld performance was studied. Short-term tensile and long-term creep tests on cross weld specimens were carried out in order to evaluate strength. The results obtained so far show that the properties of the welded joints are rather optimistic, it could be assumed that the modified Alloy 617 and the welding consumables used will meet the requirements for use in a plant operated at ultra critical steam conditions with live steam temperatures up to 720°C and pressure up to 300 bar. This allows for first practical applications in test loops of plants. These applications including the Welding Procedure Qualifications are described.

A major cost contributor of P91 pipe welding is the vital requirement of ensuring proper protection of the root or first pass of the weld from oxidation through the use of an inert gas blanket, i.e. backing gas. The necessity for oxidation protection negatively impacts the cost of both weld set-up and the actual welding process of P91 pipe fabrication. In an effort to decrease the associated costs of welding P91, Fluor Corporation has invested in significant research and extensive field-testing to develop the wire/gas mixture that contributes to the breakthrough in welding P91 with “No Backing Gas (NBG)”. Combining this novel technique with the semiautomatic GMAW-S (using inverter technology with a controlled transfer) eliminates all cost associated with the need to provide a backing gas, including installation of purge dams, backing gas, and man-hours associated with implementing these activities.

Construction of boilers that can take advantage of the higher efficiencies offered by thermodynamic cycles operating in the ultrasupercritical range will require materials having elevated temperature properties considerably superior to those of the alloys used in more conventional boilers. While many of the materials currently under consideration for ultrasupercritical boiler applications have seen use in other applications, few have been fully investigated using the product forms and section sizes required by high-temperature, high- pressure steam generators. Before any material can be considered truly applicable for use in these advanced plants, the requirements and effects of boiler industry fabrication processes must be explored in addition to determining the properties of the basic alloys. This need was recognized in a materials evaluation program sponsored by the U.S. Department of Energy and the Ohio Coal Development Office and a portion of this program has been devoted to studying the weldability of candidate ultrasupercritical boiler alloys. This paper describes the results of welding trials involving two of these alloys: Super 304H stainless steel and Controlled Chemistry Alloy 617, a variant of Inconel 617 that has been dubbed “CCA 617.” The CCA 617 was represented in both thick plate and tubular product forms, but the stainless steel was only available as tubing. Issues that might be encountered in fabricating advanced boiler headers and piping were addressed while welding the CCA 617 plate with shielded metal arc and submerged arc processes. Similarly, experience working with tubular product forms of both alloys was gained while making butt joints with an orbital gas tungsten arc process. The paper describes the problems presented, the procedures developed, and the basic characteristics of the welds produced.

In the late 1980s, the domestic utility industry experienced failures in dissimilar metal welds (DMWs) between low-alloy ferritic tubing and austenitic tubing in superheaters and reheaters. Extensive research by EPRI found that nickel-based filler metals provided significant service life improvements over 309 stainless steel filler metals. Improved joint geometries and additional weld metal reinforcement were determined to extend service life further. A new nickel-based filler metal was also developed, exhibiting thermal expansion properties similar to the low-alloy base metal and a low chromium content that would result in a smaller carbon-depleted zone than currently available fillers. However, this new filler metal was never commercialized due to a tendency for microfissuring, resulting in less than desired service life. This paper discusses further investigation into the filler metal microfissuring issue and examines long-term testing to determine the filler's suitability for high-temperature applications.

Tests show that Inconel Filler Metal 72 overlay and/or Incoclad alloys 671/800HT are two material solutions that will provide adequate corrosion and erosion protection for superheater and reheater tubes in low-NOx boilers. This paper gives an overview of the corrosion issues involved in these applications and presents test data for these materials.