The creep-fatigue properties of steam turbine materials such as the 1%CrMoV steel traditionally adopted for steam inlet temperatures up to ~565°C, the newer advanced 9-11%Cr steels for applications up to ~600°C, and the nickel based Alloy 617 for potential use to >700°C are reviewed, in particular with reference to their cyclic/hold test crack initiation endurances. The results of cyclic/hold creep-fatigue tests are commonly employed to establish the damage summation diagrams used to form the basis of a number of creep-fatigue assessment procedures, and it is demonstrated that care should be exercised in the way such diagrams are interpreted to compare the creep-fatigue resistances of different alloy types. The form of such damage diagrams is dependent, not only on the analytical procedures used to define the respective fatigue and creep damage fractions, but also on both the deformation and damage interaction mechanisms displayed by the material.

The extrapolation of short-term laboratory test results to predict long-term high-temperature component failure remains challenging, particularly for P91 steel due to its phase transformation during extended service and susceptibility to type IV cracking. While the NSW model successfully predicts creep crack growth bounds using short to medium-term test data (<10,000 hours), recent literature suggests materials may exhibit more brittle behavior and reduced failure strain in longer-term tests. This study examines whether the NSW model, using short-term uniaxial data, can effectively predict these long-term behavioral changes for more accurate service life assessment.

In this paper we tried to model the creep-strength degradation of selected advanced creep resistant steels which occurs under operating conditions. In order to accelerate some microstructure changes and thus to simulate degradation processes in long-term service, isothermal ageing at 650°C for 10 000 h was applied to P91, P92 and P23 steels in their as- received states. The tensile creep tests were performed at temperature 600°C in argon atmosphere on all steels both in the as-received state and after isothermal ageing, in an effort to obtain a more complete description of the role of microstructure stability in high temperature creep of these steels. Creep tests were followed by microstructure investigations by means of transmission and scanning electron microscopy and by the thermodynamic calculations. The applicability of the creep tests was verified by the theoretical modelling of the phase equilibrium at different temperatures. It is suggested that under restricted oxidation due to argon atmosphere microstructure instability is the main detrimental process in the long-term degradation of the creep rupture strength of these steels.

The paper describes methods for practical high temperature weldment life assessment, and their application to the analysis of notable high energy piping weldment failures and interpretation of cross-weld data. The methods described in the paper are simplified versions of full continuum damage mechanics (CDM) analysis techniques which have been developed over the last 20 years. The complexity of the CDM methods and their data requirements has been a barrier to their more widespread use. The need for simplified methods has been driven by the need for risk assessment of in-service high temperature welded piping and headers around the world, the need to connect cross-weld data to weld joint design and assessment, and in general, the need to develop suitable guidelines for evaluating the strength of weldments relative to that of base metal.

Critical sections of steam plants and heat-recovery steam generators require materials with enhanced properties such as 9Cr-1Mo steel. Ensuring compliance with specifications for heat treatment, chemical composition, contamination limits, and joint design is crucial to prevent premature failures. This study describes the development of a user-friendly, multi-property nondestructive sensor arrangement to qualify heat-treated 9Cr-1Mo steel. Experimental results demonstrate that correlations between thermal heat treatment and electronic, magnetic, and elastic measurements can determine if T91 steel achieves the necessary microstructure and properties for service. Additionally, rejected parts can be assessed for microstructural issues causing unacceptable properties. The techniques utilize a common electronic setup with different sensors, requiring calibration for specific NDE systems and sensor setups, high-speed data acquisition, and frequency analysis (FFT). Further development on crept and welded samples is recommended to enhance NDE practices for in-service T91 steel conditions.

To enhance power plant efficiency, global projects aim to increase operating temperatures to 700 °C (1292 °F) and beyond, surpassing the capabilities of conventional ferritic and austenitic steel alloys and necessitating the use of nickel-based alloys like Alloy 617. This study evaluated the fatigue and creep-fatigue performance of Alloy 617, including both parent metal and welds, at 650 °C (1202 °F). Tests were conducted on virgin material, service-aged samples (up to 25,000 hours), and material over-aged at 800 °C (1472 °F) for 1,000 hours. Results indicated that service aging only slightly reduced the pure fatigue properties of Alloy 617, but significantly decreased its life under creep-fatigue conditions. The creep-fatigue life of ex-service welds was reduced to less than one-third of that of virgin parent metal. The data suggests that the introduction of a tensile hold period impacts Alloy 617's life more than Alloy 263 but less than Alloy 740, potentially linked to the cyclic strength of the alloys. The reduction in life for Alloy 617 is notably greater than that observed in conventional ferritic alloys.

Grade 92 steel, a creep strength-enhanced ferritic (CSEF) steel, is used in supercritical steam fossil power plants for boilers and piping systems. While its creep strength is crucial, understanding the interaction between creep and fatigue damage is also vital for assessing component integrity under cyclic loading. Despite existing studies on its creep-fatigue behavior, additional data under creep-dominant conditions relevant to plant evaluations are needed. Girth welds, critical to piping system integrity, are particularly important in this context. EPRI and CRIEPI initiated a project to develop a comprehensive database on the creep-fatigue behavior of Grade 92 steel's base metal and welded joints and to establish a suitable life estimation procedure. Key findings include: (i) a thick pipe with submerged arc welding (SAW) was manufactured for testing; (ii) base metal and cross-weld specimens showed similar behavior under short-term creep and cyclic loading; (iii) these specimens had lower creep strengths than average literature values for this steel class in the short time regime, with differences decreasing as stress decreased; and (iv) the fatigue and creep-fatigue behavior of these specimens were similar to those of Grade 91 and 122 steels, with common characteristics in creep-fatigue failure prediction models across the three CSEF steels.

Advanced ultra-supercritical fossil plants operated at 700/725 °C and up to 350 bars are currently planned to be realized in the next decade. Due to the increase of the steam parameters and the use of new materials e.g. 9-11%Cr steels and nickel based alloys the design of highly loaded components is approaching more and more the classical design limits with regard to critical wall thickness and the related tolerable thermal gradients. To make full use of the strength potential of new boiler materials but also taking into account their specific stress-strain relaxation behavior, new methods are required for reliable integrity analyses and lifetime assessment procedures. Numerical Finite Element (FE) simulation using inelastic constitutive equations offers the possibility of “design by analysis” based on state of the art FE codes and user-defined advanced inelastic material laws. Furthermore material specific damage mechanisms must be considered in such assessments. With regard to component behavior beside aspects of multiaxial loading conditions must be considered as well as the behavior of materials and welded joints in the as-built state. Finally an outlook on the capabilities of new multi-scale approaches to describe material and component behavior will be given.

The highest creep rupture strength of recent 9-12% Cr steels which have seen practical application is about 130 MPa at 600°C and 100,000 h. While the 630°C goal may be realized, much more work is needed to achieve steam temperatures up to 650°C. Conventional alloy development techniques can be slow and it is possible that mathematical models can define the most economical path forward, perhaps leading to novel ideas. A combination of mechanical property models based on neural networks, and phase stability calculations relying on thermodynamics, has been used to propose new alloys, and the predictions from this work were published some time ago. In the present work we present results showing how the proposed alloys have performed in practice, considering long term creep data and microstructural observations. Comparisons are also made with existing enhanced ferritic steels such as Grade 92 and other advanced 9-12%Cr steels recently reported.

The increasing steam parameters in modern high-efficiency fossil fuel power plants demand advanced materials with enhanced creep strength for operation under extreme temperature and pressure conditions. Tenaris has focused on developing ferritic-martensitic and austenitic grades for tube and pipe applications. At TenarisDalmine, efforts on ferritic-martensitic steels include ASTM Grade 23, a low-alloyed alternative to Grade 22 with 1.5% W, offering good weldability, creep resistance up to 580°C, and cost competitiveness. Additionally, ASTM Grade 92, an improved version of Grade 91, provides high creep strength and long-term stability for components like superheaters and headers operating up to 620°C. At TenarisNKKT R&D, austenitic steel development includes TEMPALOY AA-1, an improved 18Cr-8NiNbTi alloy with 3% Cu for enhanced creep and corrosion resistance, and TEMPALOY A-3, a 20Cr-15Ni-Nb-N alloy with superior creep and corrosion properties due to its higher chromium content. This paper details the Tenaris product lineup, manufacturing processes, and key material properties, including the impact of shot blasting on the steam oxidation resistance of austenitic grades. It also covers ongoing R&D efforts in alloy design, creep testing, data assessment, microstructural analysis, and damage modeling, conducted in collaboration with Centro Sviluppo Materiali.

The paper summarizes several years of research on the application of modern materials in the design of large steam turbines operating at high temperatures. The use of 9-12% chromium steels on main steam turbine components, the application of abradable coatings in seals and the seize/corrosion protection of selected components by modern surfacing techniques are presented. Results of materials long-term testing supported by the field application at elevated steam temperatures were used to verify the new material solutions and manufacturing techniques. The second section of the paper presents the design of a new 660 MW supercritical power plant to be built in the Czech Republic between 2008 and 2010. The unit parameters and steam cycle characteristics are presented together with the visualization of the new block. The steam turbine design is discussed with respect to the application of advanced materials.

In 2004, extensive Type IV cracking was discovered in the branch and attachment welds of a modified 9Cr (Grade 91) header after 58,000 hours of service. The header, installed as a retrofit in a 500MW unit in 1992, was inspected early due to concerns over the incorporation of low nitrogen-to-aluminum (N:Al) ratio components, a factor previously linked to premature failures of this steel grade in the UK. Investigations confirmed the presence of coarse aluminum nitride (AlN) precipitates, a depleted VN-type MX precipitate population, and reduced parent and Type IV creep strength in low N:Al ratio material. Cracking predominantly occurred on the header barrel sides of the welds in material that, despite meeting ASTM compositional requirements, exhibited this unfavorable N:Al ratio. This paper summarizes the inspection history, detailing crack distribution observed in 2004 and a subsequent outage in 2006. The findings are analyzed in the context of Grade 91’s Type IV creep life shortfall and its dependence on chemical composition, with broader implications for other Grade 91 components in service.

The long-term creep strength of creep strength-enhanced ferritic steels has been overestimated due to changes in the stress dependence of creep rupture life at lower stress levels. To address this, creep rupture strength has been reassessed using a region-splitting analysis method, leading to reductions in the allowable tensile stress of these steels as per Japan’s METI Thermal Power Standard Code in December 2005 and July 2007. This method evaluates creep rupture strength separately in high and low stress regimes, divided at 50% of the 0.2% offset yield stress, which corresponds approximately to the 0% offset yield stress in ASME Grade 122-type steels. In the high-stress regime, the minimum creep rate follows the stress dependence of flow stress in tensile tests, with the stress exponent (n) decreasing from 20 at 550°C to 10 at 700°C. In contrast, the low-stress regime exhibits an n value of 4 to 6 for tempered martensitic single-phase steels, while dual-phase steels containing delta ferrite show an even lower n value of 2 to 4. The significant stress dependence of creep rupture life and minimum creep rate in the high-stress regime is attributed to plastic deformation at stresses exceeding the proportional limit. Meanwhile, creep deformation in the low-stress regime is governed by diffusion-controlled mechanisms and dislocation climb as the rate-controlling process.

This study examined a three-way steam pipe made from low-alloy cast Cr-Mo-V steel after more than 100,000 hours of creep service. The investigation compared the microstructure and mechanical properties at both room and elevated temperatures to the material's initial state, including impact transition temperatures. The research utilized shortened creep tests under various conditions of stress and temperature, along with extensive investigations of both low-alloy Cr-Mo-V and high-alloyed 12Cr-Mo-V steels, to develop methods for estimating service life and residual life in practical applications. The findings enabled the development of parameter selection methods for long-term creep tests and helped determine the residual life of the low-alloy Cr-Mo-V cast steel. Additional low-cycle isothermal and thermal fatigue tests were conducted to assess the overall degree of material property degradation, with results being applicable to the diagnostics of pressure installations in power stations.

The Institute for Materials Science, Welding and Forming (IWS) conducts extensive research on modern martensitic 9-12% Cr steels intended for use in environmentally friendly power plants. Their comprehensive research program encompasses mechanical testing of base and weld metals, analysis of creep and damage mechanisms, weldability studies, microstructural evolution during creep, mathematical modeling of precipitation and coarsening kinetics, and simulation of complex heat treatments and creep deformation behavior. Through these interconnected projects, which are briefly described, IWS develops a thorough understanding of these materials while working toward a quantitative model of their creep behavior.

Research has demonstrated that creep damage in power plant steels is directly linked to grain boundary precipitates, which serve as nucleation sites for cavities and micro-cracks. The formation of M 23 C 6 carbides along grain boundaries creates chromium-depleted zones vulnerable to corrosion and significantly reduces creep life due to rapid coarsening. Through combined Monte Carlo grain boundary precipitation kinetics and continuum creep damage modeling, researchers have predicted that increasing the proportion of MX-type particles could enhance creep performance. This hypothesis was tested using hafnium-containing steel, which showed improved creep and corrosion properties in 9% Cr steels. Ion implantation of Hafnium into thin foils of 9 wt% Cr ferritic steel resulted in two new types of precipitates: hafnium carbide (MX-type) and a Cr-V rich nitride (M 2 N). The hafnium carbide particles, identified through convergent beam diffraction and microanalysis, appeared in significantly higher volume fractions compared to VN in conventional ferritic steels. Additionally, Hafnium was found to eliminate M 23 C 6 grain boundary precipitates, resulting in increased matrix chromium concentration, reduced grain boundary chromium depletion, and enhanced resistance to intergranular corrosion cracking.

A comprehensive EPRI initiative launched in 2006 has addressed the critical need to better understand creep-fatigue interactions in power plants experiencing cyclic operation. This international collaboration of industry experts has focused on evaluating current test methods, analyzing crack initiation and growth methodologies, examining life prediction approaches for various applications, identifying deficiencies in creep-fatigue damage assessment, and determining future research requirements. This paper presents key findings from the project, with particular attention to the performance of creep-strengthened ferritic steels, specifically Grade 91 and 92 steels, providing essential insights for power plants facing increasingly demanding operational conditions.

TAF steel is a Japanese high-boron 10.5% Cr martensitic stainless steel known for its exceptional high-temperature creep strength. Its high boron content (300-400 ppm) limited practical applications due to reduced hot workability in large turbine components. Recent research suggests that increasing boron content while adjusting nitrogen levels could enhance creep properties by promoting fine vanadium carbonitride formation while preventing boron nitride formation. This study presents microstructural investigations, particularly using transmission electron microscopy, focusing on precipitation characteristics and long-term precipitate evolution within the COST 536 framework.

Procedures for assessing components subjected to cyclic loading at high temperatures require material property data that characterize creep-fatigue deformation behavior and resistance to cracking. While several standards and codes define test procedures for acquiring low cycle fatigue (LCF) and creep properties, no formal guidelines exist for determining creep-fatigue data. This paper reviews the results of a global survey conducted by EPRI to support the development of a new draft testing procedure intended for submission to ASTM and, ultimately, ISO standards committees. The survey included a review of relevant national and international standards, as well as responses to a questionnaire distributed to high-temperature testing specialists in Europe, North America, and Japan. Additionally, standards related to the calibration of load, extension, and temperature measurement devices were examined. The questionnaire responses provided insights into test specimen geometry, testing equipment, control and measurement of load, extension, and temperature, and data acquisition practices. This paper outlines the background and considerations for the proposed guidance in the new standard.

The European Creep Collaborative Committee Working Group on Austenitic Stainless Steels (WG3B) has conducted comprehensive reviews of existing rupture strength values, compiled data for both existing and new grades of austenitic steels, and performed new assessments of rupture strength for these materials. Specifically, new creep rupture data assessments have been carried out for TP316L, TP316, Alloy 800H, Alloy 800HT, 253MA, Esshete 1250, HR3C, NF709, and NF709R. Various data analysis methods were applied by different assessors, and notably, most encountered similar challenges in simultaneously fitting high-stress, low-temperature data and low-stress, high-temperature data. These difficulties are consistent with those observed in assessments of modified 9Cr and 12Cr alloys. This paper summarizes WG3B’s experiences with such complex datasets and proposes several potential solutions to address these challenges.