The Chinese power industry has experienced rapid development in the past decade. The newly built 600+°C ultra-super-critical (UCS) fossil fire power plants and pressed water reactor nuclear power plants in China are the world’s most advanced level technically and effectively. The available capacity of 600+°C UCS fossil fire power plant in China is more than 200 GW by the end of 2015, which has greatly contributed to the energy-saving and emission-reduction for China and the whole world. In China, the 610°C and 620°C advanced USC (A-USC) fossil fire power plants had been combined into the grid, 630°C A-USC fossil fire power plant is about to start to build, the feasibility of 650°C A-USC fossil fire power plant is under evaluation, 700°C AUSC fossil fire power plant has been included in the national energy development plan and the first Chinese 700°C A-USC testing rig had been put into operation in December 2015. The advanced heat resistant materials are the bottlenecking to develop A-USC fossil fire power plant worldwide. In this paper, the research and development of candidate heat resistant steels and alloys selected and/or used for 600+°C A-UCS fossil fire power plant in China is emphasized, including newly innovated G115 martensitic steel used for 630°C steam temperature, C-HRA-2 fully solid-solution strengthening nickel alloy used for 650°C steam temperature, C-HRA-3 solid-solution strengthening nickel alloy used for 680°C steam temperature, 984G iron-nickel alloy used for 680°C steam temperature, C-HRA-1 precipitation hardening nickel alloy and C700R1 solid-solution strengthening nickel alloy used for 700+°C steam temperature.

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